이진우

Recent advances in the power conversion efficiency (PCE) of organic solar cells (OSCs) have greatly enhanced their commercial viability. Considering the technical standards (e.g., mechanical robustness) required for wearable electronics, which are promising application platforms for OSCs, the development of fully stretchable OSCs (f-SOSCs) should be accelerated. Here, a comprehensive overview of f-SOSCs, which are aimed to reliably operate under various forms of mechanical stress, including bend

Abstract All‐polymer solar cells (all‐PSCs) are a highly attractive class of photovoltaics for wearable and portable electronics due to their excellent morphological and mechanical stabilities. Recently, new types of polymer acceptors ( P A s) consisting of non‐fullerene small molecule acceptors (NFSMAs) with strong light absorption have been proposed to enhance the power conversion efficiency (PCE) of all‐PSCs. However, polymerization of NFSMAs often reduces entropy of mixing in PSC blends and

We develop an effective strategy to obtain polymer solar cells with high power conversion efficiency (17%) and remarkable mechanical robustness, by design of polymer donors with aliphatic flexible spacer incorporated into a rigid backbone.

High power conversion efficiency (PCE) and long-term stability are important requirements for commercialization of organic solar cells (OSCs). In this study, we demonstrate efficient (PCE = 18.60%) and stable (t80% lifetime > 4000 h) OSCs by developing a series of dimerized small-molecule acceptors (DSMAs). We prepared three different DSMAs (DYT, DYV, and DYTVT) by using different linkers (i.e., thiophene, vinylene, and thiophene– vinylene– thiophene), to connect their two Y-based building block

Intrinsically stretchable organic solar cells (IS-OSCs), consisting of all stretchable layers, are attracting significant attention as a future power source for wearable electronics. However, most of the efficient active layers for OSCs are mechanically brittle due to their rigid molecular structures designed for high electrical and optical properties. Here, a series of new polymer donors (P_D s, PhAmX) featuring phenyl amide (N¹ ,N³ -bis((5-bromothiophen-2-yl)met

We report a new molecular design of sequentially regular polymerized small-molecule-acceptors containing flexible spacer (FS) units (PYFS-Reg) to achieve all-polymer solar cells with both high-performance and mechanical stretchability.

We report a new trimer acceptor (TYT) composed of three Y-based molecules connected by electron-donating spacers. The TYT enables a high-performance and stable organic solar cell (OSC) with a t 80% lifetime >8000 h under 1 sun illumination.

High power conversion efficiency (PCE) and long-term stability are essential prerequisites for the commercialization of polymer solar cells (PSCs). Small-molecule acceptors (SMAs) are core materials that have led to recent, rapid increases in the PCEs of the PSCs. However, a critical limitation of the resulting PSCs is their poor long-term stability. Blend morphology degradation from rapid diffusion of SMAs with low glass transition temperatures (<i>T</i>_gs) is considered the main cau

Abstract Blends of polymer donors ( P D s) and small molecule acceptors (SMAs) have afforded highly efficient polymer solar cells (PSCs). However, most of the efficient PSCs are processed using toxic halogenated solvents, and they are mechanically fragile. Here, a new series of P D s by incorporating a hydrophilic oligo(ethylene glycol) flexible spacer (OEG‐FS) is developed, and efficient PSCs with a high power conversion efficiency (PCE) of 17.74% processed by a non‐halogenated solvent are demo

Abstract Organic solar cells (OSCs) are promising wearable/stretchable power sources, but the development of high‐performance intrinsically stretchable OSCs (IS‐OSCs) has rarely been reported. Herein, IS‐OSCs exhibiting high power conversion efficiencies (PCEs) (&gt;12%) and excellent stretchability are developed by constructing efficient and mechanically robust active layers via the addition of a high‐molecular weight polymer acceptor ( P A ) to polymer donor:small‐molecule acceptor blends. P A

Abstract High power conversion efficiency (PCE), long‐term stability, and mechanical robustness are prerequisites for the commercial applications of organic solar cells (OSCs). In this study, a new star‐shaped trimer acceptor (TYT‐S) is developed and high‐performance OSCs with a PCE of 19.0%, high photo‐stability ( t 80% lifetime = 2600 h under 1‐sun illumination), and mechanical robustness with a crack‐onset strain (COS) of 21.6% are achieved. The isotropic molecular structure of TYT‐S affords

We report a series of new n-type random copolymers (P(NDI2OD-Se-Th x), where x = 0, 0.5, 0.7, 0.8, 0.9, 1.0) consisting of naphthalene diimide (NDI), selenophene-2,2′-thiophene (Se-Th), and seleno[3,2-b]thiophene (SeTh) to demonstrate their use in producing efficient all-polymer solar cells (all-PSCs) and organic field-effect transistors (OFETs). To investigate the effect of polymer crystallinity on the performance of all-PSCs and OFETs, we tuned the composition of the Se-Th and SeTh moieties in

Small-molecule acceptor (SMA)-based organic solar cells (OSCs) have achieved high power conversion efficiencies (PCEs), while their long-term stabilities remain to be improved to meet the requirements for real applications. Herein, we demonstrate the use of donor-acceptor alternating copolymer-type compatibilizers (DACCs) in high-performance SMA-based OSCs, enhancing their PCE, thermal stability, and mechanical robustness simultaneously. Detailed experimental and computational studies reveal tha

The recent evolution of new polymer acceptors (PAs) using small-molecule building blocks with high light absorption has significantly increased the power conversion efficiency (PCE) of all-polymer solar cells (all-PSCs), but their mechanical properties are typically poor. Thus, poly[[N,N′-bis(2-octyldodecyl)-naphthalene-1,4,5,8-bis(dicarboximide)-2,6-diyl]-alt-5,5′-(2,2′-bithiophene)] (N2200) is still considered one of the most successful PAs in all-PSCs. Herein, we report the development of new