Kentaro Yamamoto

This paper focuses mainly on the stability of a square tunnel in cohesive–frictional soils subjected to surcharge loading. Large-size noncircular tunnels are quickly becoming a widespread building technology by virtue of the development of advanced tunneling machines. The stability of square tunnels in cohesive–frictional soils subjected to surcharge loading has been investigated theoretically and numerically, assuming plane strain conditions. Despite the importance of this problem, previous res

For the further development of lithium-ion batteries, improvement of their cyclic performance is crucial. However, the mechanism underlying the deterioration of the battery cyclic performance is not fully understood. We investigated the effects of the electronic structure at the electrode/electrolyte interface on the cyclic performance of the cathode materials via in situ total-reflection fluorescence X-ray absorption spectroscopy. In a LiCoO2 thin-film electrode that exhibits gradual deteriorat

Fluoride ion batteries (FIBs) are regarded as promising energy storage devices, and it is important and urgent to develop cathode materials with high energy densities for use in FIBs.

Recently, several sulfide solid electrolytes have been synthesized by liquid-phase synthesis for the commercialization of all-solid-state batteries. Unfortunately, the ionic conductivity for most of these electrolytes is unsatisfactory compared to that of solid electrolytes synthesized by conventional ball milling. This problem is attributed to different mechanisms between the liquid phase and the solid phase in reaction and formation. However, to the best of our knowledge, the effect of the sol

The stability of dual square tunnels in cohesive-frictional soils subjected to surcharge loading has been investigated theoretically and numerically assuming plane strain conditions. From the viewpoint of the efficient utilization of underground space for human activities, noncircular openings and tunnels should be preferred in the design stage. Despite the importance of this issue, previous research on the subject is very limited. At present, no generally accepted design or analysis method is a

The charge/discharge capacity of current lithium-ion battery cathode materials is limited by the charge compensation of transition-metal redox during the charge/discharge processes. Recently, the use of oxide ion redox for charge compensation has been proposed to realize a higher charge/discharge capacity than that observed for transition-metal redox. Different stabilization mechanisms of the reversible oxide ion redox have been proposed. To clarify the mechanism, analysis of the electronic and

Abstract All‐solid‐state fluoride‐ion batteries (FIBs) are regarded as promising energy storage devices; however, currently proposed cathodes fail to meet the requirements for practical applications in terms of high energy density and high rate capability. Herein, the first use of stable and low‐cost cuprous oxide (Cu 2 O) as a cathode material for all‐solid‐state FIBs with reversible and fast (de)fluorination behavior is reported. A phase‐transition reaction mechanism involving Cu + /Cu 2+ redo

Developing electrochemical high-energy storage systems is of crucial importance toward a green and sustainable energy supply. A promising candidate is fluoride-ion batteries (FIBs), which can deliver a much higher volumetric energy density than lithium-ion batteries. However, typical metal fluoride cathodes with conversion-type reactions cause a low-rate capability. Recently, layered perovskite oxides and oxyfluorides, such as LaSrMnO₄ and Sr₃Fe₂O₅F<su

To clarify the origin of the polarization of magnesium deposition/dissolution reactions, we combined electrochemical measurement, <i>operando</i> soft X-ray absorption spectroscopy (<i>operando</i> SXAS), Raman, and density functional theory (DFT) techniques to three different electrolytes: magnesium bis(trifluoromethanesulfonyl)amide (Mg(TFSA)₂)/triglyme, magnesium borohydride (Mg(BH₄)₂)/tetrahydrofuran (THF), and Mg(TFSA)₂/2-methyltetrahydrofuran (2-