Kuk Young Cho

A class of imprintable, bendable, and shape-conformable polymer electrolyte with excellent electrochemical performance in a lithium battery system is reported. The material consists of a UV-cured polymer matrix, high-boiling point liquid electrolyte, and Al2O3 nanoparticles, formulated for use in lithium-ion batteries with 3D-structured electrodes or flexible characteristics. The unique structural design and well-tuned rheological characteristics of the UV-curable electrolyte mixture, in combina

Abstract A high‐energy‐capacity, flexible lithium‐ion battery is fabricated using a new nanofibril‐structured silicon anode on a flexible current collector. Silicon is known to be the highest capacity anode material. However, its huge volume changes during the lithium insertion and extraction results in pulverization, which is the cause of the rapid capacity fade that occurs as the charge‐discharge cycles progress. Nanostructured silicon can overcome this pulverization problem. A flexible curren

Simple oil-in-water emulsion led to structural complexity at both the surface and interior of the PLGA microsphere. A golf ball-like dimpled surface comes from the heteroaggregation of volatile nonsolvent colloid originating from the inside of the organic droplet as supported by in situ optical microscopy. The internal porous structure and encapsulation of hydrophobic agent inside the microparticle implies its potential application as a drug carrier.

A flexible hybrid anode from graphite and thin film silicon is realized by the concept of a 3D sandwich current collector by the combination of micro-contact printing and RF magnetron sputtering. Flexible lithium-ion batteries with a new hybrid anode demonstrate not only enhanced specific capacity but also improved rate capability compared to that of a conventional graphite anode under bending deformation.

Abstract The development of lithium metal anodes for next generation batteries remains a challenge. Uncontrolled Li dendrite growth not only induces severe safety issues but also leads to capacity fading by continuously consuming the electrolyte. This study demonstrates the design and fabrication of a composite protective layer composed of a high dielectric polymer, inorganic particles, and an electrolyte to overcome these obstacles. This layer not only suppresses dendrite growth, but also preve

Next-generation lithium-ion batteries (LIBs) that satisfy the requirements for an electric vehicle energy source should demonstrate high reliability and safety for long-term high-energy-density operation. This inevitably calls for a novel approach to advance major components such as the separator. Herein, a separator is designed and fabricated via application of multilayer functional coating on both sides of a polyethylene separator. The multilayer-coated separator (MCS) has a porous structure t

As a representative in the post-lithium-ion batteries (LIBs) landscape, lithium metal batteries (LMBs) exhibit high-energy densities but suffer from low coulombic efficiencies and short cycling lifetimes due to dendrite formation and complex side reactions. Separator modification holds the most promise in overcoming these challenges because it utilizes the original elements of LMBs. In this review, separators designed to address critical issues in LMBs that are fatal to their destiny according t

We demonstrate the new fabrication of uniform polymer microparticles exhibiting not only an internal porous structure but also a golf-ball-like dimple pattern on the surface. The method provides a simple route for engineering the physical aspects of microparticles and can also be applied to various polymers that have been a continuous challenge in microparticle engineering. The final appearance of the porous structure interior of the microparticles was determined by the selection of amorphous or

Abstract Phosphor‐in‐glass (PiG) thick film was fabricated on a borosilicate glass substrate using a conventional screen printing method and employing phosphosilicate glass to allow low‐temperature sintering. The vehicle content and sintering temperature were optimized to form a thick film with a thickness of ~50 μm. Commercial yellow (Y 3 Al 5 O 12 :Ce 3+ ) and red (CaAlSiN 3 :Eu 2+ ) phosphors were successfully incorporated within the glass matrix and then sintered at 550°C. Color‐tunable whit

Initial reversibility and excellent capacity retention are the key requirements for the success of high-capacity electrode materials in high-performance Li-ion batteries and pose a number of challenges to development. Silicon has been regarded as a promising anode material because of its outstanding theoretical capacity. However, it suffers from colossal volume change and continuous formation of unstable solid electrolyte interphases during lithiation/delithiation processes, which eventually res