Kim Jongsik

Phosphate adsorption on the surfaces of the iron oxyhydroxide polymorphs goethite, akaganeite, and lepidocrocite were studied by using 31P static spin-echo mapping NMR experiments to determine how this environmentally-important anion binds to common soil minerals. The large 31P hyperfine shifts confirm the formation of inner-sphere complexes between the phosphate anion and the iron oxyhydroxide surface, the large shifts indicating the presence of Fe3+–O–P covalent bonds. Binding was explored as

Iron phosphates (FePO(4)) are among the most promising candidate materials for advanced Li-ion battery cathodes. This work reports upon a combined nuclear magnetic resonance (NMR) experimental and periodic density functional theory (DFT) computational study of the environments and electronic structures occurring in a range of paramagnetic Fe(III) phosphates comprising FePO(4) (heterosite), monoclinic Li(3)Fe(2)(PO(4))(3) (anti-NASICON A type), rhombohedral Li(3)Fe(2)(PO(4))(3) (NASICON B type),

Plasma-assisted catalysis populates vibrationally excited CH₄ interacting with catalyst, leading to small energy barriers and enhanced rates to activate CH₄.

Recent shale gas discoveries and advances in plasma chemistry provide the basis to exploit metal surface–plasma interactions to precisely control C–H bond activation on catalytic surfaces, leading to improved reaction efficiencies. Although the exact determination of plasma–catalyst interactions remains a topic of continuing research, this Letter provides evidence that plasma–catalyst interactions exist and can be used to significantly enhance the activation of C–H bonds at temperatures >630 K,

2H and 7Li MAS NMR spectroscopy techniques were applied to study the local surface and bulk environments of iron oxyhydroxide lepidocrocite (gamma-FeOOH). 2H variable-temperature (VT) MAS NMR experiments were performed, showing the presence of short-range, strong antiferromagnetic correlations, even at temperatures above the Néel temperature, T(N), 77 K. The formation of a Li+ inner-sphere complex on the surface of lepidocrocite was confirmed by the observation of a signal with a large 7Li hyper

This work describes a novel method for the preparation of titanium oxide nanoparticles supported on amorphous carbon with nanoporosity (Ti/NC) via the post-synthetic modification of a Zn-based MOF with an amine functionality, IRMOF-3, with titanium isopropoxide followed by its carbothermal pyrolysis. This material exhibited high purity, high surface area (>1000 m(2)/g), and a high dispersion of metal oxide nanoparticles while maintaining a small particle size (~4 nm). The material was shown to b

Although the chemopreventive and antitumorigenic activities of nonsteroidal anti-inflammatory drug (NSAID) against colorectal cancer are well established, the molecular mechanisms responsible for these properties in ovarian cancer have not been elucidated. Therefore, there is an urgent need to develop mechanism-based approaches for the management of ovarian cancer. To this end, the effect of several NSAIDs on ovarian cancer cells was investigated as assessed by the induction of NAG-1/MIC-1/GDF-1

Based on the important role of microRNA (miRNA) biosynthesis genes in carcinogenesis, we hypothesized that polymorphisms in the miRNA biosynthesis genes may modulate susceptibility to lung cancer. To test this hypothesis, we conducted a two-stage study to evaluate the associations between single nucleotide polymorphisms (SNPs) in the miRNA biosynthesis genes and the risk of lung cancer. In stage 1 of the study, 24 SNPs in the 11 miRNA biosynthesis genes (DROSHA, DGCR8, RAN, XPO5, DICER, AGO1, AG

Fe₂V₄O₁₃ outperforms FeVO₄ as an active site for NH₃-SCR and resists SO₂/ABS/Na poisons with the inclusion of an Sb promoter.

2 H and 7 Li MAS NMR spectroscopy have been applied to characterize the surface and bulk hydroxyl groups and Li + sorption on the iron oxyhydroxide akaganeite (β-FeOOH), a common soil mineral with a large surface area and uptake capacity for toxic cations and anions. The formation of both inner and outer-sphere complexes on the surface of akaganeite was confirmed, the former giving rise to 7 Li NMR signals with large 7 Li hyperfine shifts. The concentrations of these complexes was determined as