Kyung Hee University · Engineering
Professor Bright Walker's research lab focuses on the development and optimization of solution-processable organic and hybrid semiconductors for next-generation optoelectronic devices, with a strong emphasis on organic solar cells and perovskite-based photovoltaics. The lab investigates molecular design principles for small-molecule donors, fullerene and non-fullerene acceptors, and solvent engineering to achieve high-performance bulk heterojunction films with improved morphology and reproducibility. A key direction involves tuning electronic and solubility properties through molecular architecture and halide composition control in perovskite materials to enhance device efficiency and stability.
Figures are computed from collected data and may differ slightly.
Although most research in the field of organic bulk heterojunction solar cells has focused on combinations of a p-type conducting polymer as a donor and a fullerene-based acceptor, recent work has demonstrated the viability of solution-processed heterojunctions composed entirely of molecular solids. Molecular solids offer potential advantages over conjugated polymer systems in terms of easier purification, amenability to mass-scale production and better batch-to-batch reproducibility. This artic
Abstract Research relating to organic solar cells based on solution‐processed, bulk heterojunction (BHJ) films has been dominated by polymeric donor materials, as they typically have better film‐forming characteristics and film morphology than their small‐molecule counterparts. Despite these morphological advantages, semiconducting polymers suffer from synthetic reproducibility and difficult purification procedures, which hinder their commercial viability. Here, a non‐polymeric, diketopyrrolopyr
Abstract The solubilities of 3,6‐bis(5‐(benzofuran‐2‐yl)thiophen‐2‐yl)‐2,5‐bis(2‐ethylhexyl)pyrrolo[3,4‐c]pyrrole‐1,4‐dione ( DPP(TBFu) 2 ) and [6,6]‐phenyl‐C 71 ‐butyric acid methyl ester ( PC 71 BM ) in a series of solvents are measured, and this data is used to calculate the Hansen solubility parameters of the two materials. The dispersion, polar, and H‐bonding parameters of DPP(TBFu) 2 and PC 71 BM were found to be (19.3, 4.8, 6.3) and (20.2, 5.4, 4.5) MPa 1/2 , respectively, with an error o
We report a series of solution-processable, small-molecule, donor materials based on an architecture consisting of two diketopyrrolopyrrole (DPP) cores with different aromatic π-bridges between the DPP units and different end-capping groups. In general, this architecture leads to desirable light absorption and electronic levels for donor materials. Out of the compounds investigated, a material with a hydrolyzed dithieno(3,2-b;2′,3′-d)silole (SDT) core and 2-benzofuran (BFu) end capping groups le
The emerging class of lead halide perovskite (LHP) semiconductors offers a surprising combination of low cost, ease of preparation, outstanding material properties, and performance in optoelectronic devices that has not yet been observed in any other class of material. Considering their general ABX<sub>3</sub> formula, the halide (X) composition in LHP compositions has proven to be one of the best handles to control the material characteristics such as bandgap, morphology, and electronic propert
Electron transport layers are used to minimize energetic barriers to electron injection and extraction in methylammonium lead bromide films, allowing photocurrent generation and light emission from “peroptronic” light-emitting solar cells.
Although one of the most attractive aspects of organic solar cells is their low cost and ease of fabrication, the active materials incorporated into the vast majority of reported bulk heterojunction (BHJ) solar cells include a semiconducting polymer and a fullerene derivative, classes of materials which are both typically difficult and expensive to prepare. In this study, we demonstrate that effective BHJs can be fabricated from two easily synthesized dye molecules. Solar cells incorporating a d
Hybrid organic–inorganic perovskites (HOIPs) have attracted considerable attention for their scientific and technological potential in photovoltaics and optoelectronic devices.
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