Tohoku University · Engineering
Professor Chunzhong Li's research lab specializes in the design, synthesis, and application of advanced nanomaterials for energy storage and conversion technologies. The lab focuses on developing carbon-based nanomaterials such as graphene quantum dots, hierarchical porous nanostructures, and hybrid nanocomposites for supercapacitors and lithium-ion batteries. Key research directions include enhancing electrical conductivity, surface functionality, and structural stability to achieve high energy and power densities. The lab also explores luminescent carbon nanomaterials with unique optical properties for potential applications in bioimaging and optoelectronics.
Figures are computed from collected data and may differ slightly.
Similar to the popular older cousins, luminescent carbon dots (C-dots), graphene quantum dots or graphene quantum discs (GQDs) have generated enormous excitement because of their superiority in chemical inertness, biocompatibility and low toxicity. Besides, GQDs, consisting of a single atomic layer of nano-sized graphite, have the excellent performances of graphene, such as high surface area, large diameter and better surface grafting using π-π conjugation and surface groups. Because of the stru
Supercapacitors have attracted intense attention due to their great potential to meet the demand of both high energy density and power density in many advanced technologies. Various carbon-based nanocomposites are currently pursued as supercapacitor electrodes because of the synergistic effect between carbon (high power density) and pseudo-capacitive nanomaterials (high energy density). This feature article aims to review most recent progress on 3D (3D) carbon based nanostructures for advanced s
A facile hydrazine hydrate reduction of graphene oxide (GO) with surface-passivated by a polyethylene glycol (PEG) method for the fabrication of graphene quantum dots (GQDs) with frequency upconverted emission is presented. And we speculate on the upconversion luminescence due to the anti-Stokes photoluminescence (ASPL), where the δE between the π and σ orbitals is near 1.1 eV.
Supercapacitors have attracted huge attention in recent years as they have the potential to satisfy the demand of both huge energy and power density in many advanced technologies. However, poor conductivity and cycling stability remains to be the major challenge for its widespread application. Various strategies have been developed for meeting the ever-increasing energy and power demands in supercapacitors. This Research News article aims to review recent progress in the development of mesoporou
We demonstrate a simple and scalable strategy for synthesizing hierarchical porous NiCo(2)O(4) nanowires which exhibit a high specific capacitance of 743 F g(-1) at 1 A g(-1) with excellent rate performance (78.6% capacity retention at 40 A g(-1)) and cycling stability (only 6.2% loss after 3000 cycles).
A novel strategy for the controlled synthesis of 2D MoS2/C hybrid nanosheets consisting of the alternative layer-by-layer interoverlapped single-layer MoS2 and mesoporous carbon (m-C) is demonstrated. Such special hybrid nanosheets with a maximized MoS2 /m-C interface contact show very good performance for lithium-ion batteries in terms of high reversible capacity, excellent rate capability, and outstanding cycling stability.
Transition metal nanoparticles (Fe, Co, and Ni) encapsulated in N-doped carbon nanotube hybrids were prepared, and the catalytic activities of three catalysts are compared and discussed. The optimized Co/N-CNT catalyst exhibits superb bifunctional catalytic activity with a Δ<italic>E</italic>value of 0.78 V.
Uniform Ni(OH)2 hierarchical nanostructures, assembled from ultrathin nanoflakes with thickness of only ∼7.4 nm, are designed and investigated as electrochemical pseudo-capacitor materials for potential energy storage applications. The ultrathin nanostructures exhibit a highest specific capacitance of 1715 F g−1 at a scan rate of 5 mV s−1 within the potential range of 0.6 V with high rate capability and good cycling stability. The high specific capacitance and remarkable rate capability are prom
This review summarizes the recent progress of atomic heterointerface engineering to overcome the activity limitation of electrocatalysts for water splitting and elaborates its electron effect and ensemble effect, etc.
A flexible and robust electrode is demonstrated by assembling the 3D ordered macroporous MoS2@C nanostructure on carbon cloth with ultrasmall few-layered MoS2 nanosheets homogenously embedded into the interconnected carbon wall. Such unique nanostructures are favorable for enhancing lithium storage capacity, directly applied as a flexible electrode, demonstrating a very high electrochemical performance and superior cycling stability for lithium-ion batteries. As a service to our authors and read
In this paper, using manganese oxide as an example, we report the successful design and synthesis of a novel one-dimensional highly graphitic carbon-tipped manganese oxide/mesoporous carbon/manganese oxide hybrid nanowire. The unique structure significantly improves the conductivity of metal oxide materials, which is a key limitation in pseudocapacitors. The hybrid nanowire with optimal carbon content, when applied as an electrode, exhibits superior capacitive properties in 1 M Na2SO4 aqueous so
Electrocatalytic reactions occur in the nanoscale space at the electrified electrode-electrolyte interface. It is well known that the electrode-electrolyte interface, also called as interfacial microenvironment, is difficult to investigate due to the interference of bulk electrolytes and its dynamic evolution in response to applied bias potential. Here, we employ electrochemical co-reduction of CO<sub>2</sub> and H<sub>2</sub>O on commercial Ag electrodes as a model system, in conjunction with q
A green asymmetric supercapacitor with high energy density has been developed using birnessite-type ultrathin porous MnO(2) nanoflowers (UBMNFs) as positive electrode and functional mesoporous carbon nanotubes (FMCNTs) as negative electrode in 1 M Na(2)SO(4) electrolyte. Both of the electrode materials possess excellent electrochemical performances, with high surface areas and narrow pore size distributions. More significantly, the assembled asymmetric supercapacitor with optimal mass ratio can
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