Nicolas Clément

Low-frequency noise is used to study the electronic transport in arrays of 14 nm gate length vertical silicon nanowire devices. We demonstrate that, even at such scaling, the electrostatic control of the gate-all-around is sufficient in the sub-threshold voltage region to confine charges in the heart of the wire, and the extremely low noise level is comparable to that of high quality epitaxial layers. Although contact noise can already be a source of poor transistor operation above threshold vol

We present a quantitative exploration, combining experiment and simulation, of the mechanical and electronic properties, as well as the modifications induced by an alkylthiolated coating, at the single nanoparticle (NP) level. We determined the response of the NPs to external pressure in a controlled manner using an atomic force microscope tip. We found a strong reduction in their Young's modulus, as compared to bulk gold, and a significant influence of strain on the electronic properties of the

Investigation of low-frequency noise in nanoscale Schottky-barrier (SB)-based field-effect transistors (SB-FETs) is of prime importance due to its large amplitude in emerging bottom-up devices. In addition, noise can give additional information on charge transport mechanisms. In this paper, we study the 1/ <i xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">f</i> noise in nanoscale silicon-on-insulator SB-FETs. An unexpected feature is the clear contribut

The mechanism responsible for electron transport within layers of redox DNA anchored to electrodes has been extensively studied over the last twenty years, but remains controversial. Herein, we thoroughly study the electrochemical behavior of a series of short, model, ferrocene (Fc) end-labeled dT oligonucleotides, terminally attached to gold electrodes, using high scan rate cyclic voltammetry complemented by molecular dynamics simulations. We evidence that the electrochemical response of both s

Electrochemical microscopy techniques have extended the understanding of surface chemistry to the micrometer and even sub-micrometer level. However, fundamental questions related to charge transport at the solid-electrolyte interface, such as catalytic reactions or operation of individual ion channels, require improved spatial resolutions down to the nanoscale. A prerequisite for single-molecule electrochemical sensitivity is the reliable detection of a few electrons per second, that is, current

We study the dynamic electrical response of a silicon-molecular monolayer-metal junctions and we observe two contributions in the admittance spectroscopy data. These contributions are related to dipolar relaxation and molecular organization in the monolayer in one hand, and the presence of defects at the silicon/molecule interface in the other hand. We propose a small signal equivalent circuit suitable for the simulations of these molecular devices in commercial device simulators. Our results co

This paper describes a novel simple and inexpensive assembly technique with highly accurate alignment of a polydimethylsiloxane (PDMS) layer on a silicon chip for hybrid microfluidic/electronic applications. It is based on strong electrostatic adhesion of a 200 μm thick and dense layer of PDMS onto a metallic cylindrical tool mechanically fixed to an optical microscope. A 2 mm hole in the tool allows precise alignment of the PDMS layer, 10 μm from the surface, without the usage of any lubricant.

This article presents a comparative study of the arrowheads found in graves dating to between 2500 BC and 1700 bc in north-west France, southern Britain and Denmark. The aim is to characterise their modes of production and functions during a period which successively sees the introduction of copper then bronze metallurgy, the former accompanying the appearance of Bell Beaker pottery and associated practices in these areas. Several modes of production are proposed, from individual manufacture by

We hereby report the synthesis, crystal structures and magnetic characterizations of three novel Cr(III) complexes: a mononuclear Cr(III)(HL((1)))₃ species along with two dinuclear μ-methoxo Cr(III)₂(μ-OMe)₂(HL)₄ (H₂L((1)): 2-salicyloylhydrazono-1,3-dithiolane; H₂L((2)): 2-salicyloylhydrazono-1,3-dithiane). EPR studies indicate that both dinuclear complexes (2a and 2b) are stable in solution (CHCl₃). Both Cr(III) dinuclear complexes exhibit a strong antiferromagnetic coupling. DFT calculations p

An evaluation of the gate capacitance of a field-effect transitor (FET), whose channel length and width are several ten nanometer, is a key point for sensors applications. However, experimental and precise evaluation of capacitance in the attofarad range or less has been extremely difficult. Here, we report an extraction of the capacitance down to 0.55 aF for a Si FET with a nanoscale wire channel, whose width and length are 15 and 50 nm, respectively. The extraction can be achieved by using a c

En 1843, Arthur Boutarel, inspecteur des forêts de Lorient, fouille un tumulus dans la forêt de Carnoët, près du hameau de Lothéa (Quimperlé, Finistère). La découverte de la relation de fouilles, restée inédite durant près de 170 ans, porte à une révision de cette tombe à la lumière des avancées de la recherche. Le tertre, par sa taille, appartient aux grands tumulus de l’Âge du Bronze ancien de Bretagne. Le caveau funéraire est construit selon les principes de l’architecture mégalithique et peu

Brittany can pride itself on the Armorican arrowheads found in Early Bronze Age graves (2150-1700 BC). In the present state of knowledge, these are the only specialized craft products in knapped flint produced in this region at the western edge of continental Europe. Admired since the 19th century, these flint arrowheads have never really been studied. Due to the wealth of graves and grave-goods, a relatively precise study can be undertaken of the development of these craft products, despite the

Theoretical treatments of polymer dynamics in liquid generally start with the basic assumption that motion at the smallest scale is heavily overdamped; therefore, inertia can be neglected. We report on the Brownian motion of tethered DNA under nanoconfinement, which was analyzed by molecular dynamics simulation and nanoelectrochemistry-based single-electron shuttle experiments. Our results show a transition into the ballistic Brownian motion regime for short DNA in sub-5 nm gaps, with quality co