The University of Tokyo · 재료과학
Bin Feng 교수의 연구실은 원자 체계에서의 결함, 특히 격자 결함과 상경계의 구조적·화학적 이질성이 재료의 거시적 기계적, 전기적, 이온 전도성 등 기능성에 미치는 영향을 원자 해상도로 규명하는 데 초점을 맞추고 있습니다. 주로 YSZ(yttria-stabilized zirconia)를 모델 재료로 삼아, 원자별 도핑 원소의 상경계 분포, 산소 공석, 비정상 결함 등이 전도성 및 반응성에 미치는 영향을 전자현미경 및 이론 계산을 융합하여 연구합니다. 특히 원자 해상도 에너지 분산 X선 분석(EDS)과 스캐닝 투과전자현미경(STEM)을 기반으로 한 정량적 분석 기법을 핵심으로 삼고 있습니다.
표시된 성과는 수집된 데이터 기준으로 산출되며, 일부 차이가 있을 수 있습니다.
Grain boundary segregation is a critical issue in materials science because it determines the properties of individual grain boundaries and thus governs the macroscopic properties of materials. Recent progress in electron microscopy has greatly improved our understanding of grain boundary segregation phenomena down to atomistic dimensions, but solute segregation is still extremely challenging to experimentally identify at the atomic scale. Here, we report direct observations of atomic-scale yttr
Nanostructuring and second phase incorporation are considered to be promising ways of enhancing the thermoelectric performance of bulk materials. Here, a design principle is proposed which combines these two methods for improving the thermoelectric performance of p-type CoSb3 by fabricating a CoSb3/graphene (CoSb3/G) nanocomposite, where a second phase, graphene, is introduced in the nanostructured CoSb3 matrix via an in situ one-pot solvothermal route. In addition, CoSb3/G bulk materials were p
Material performance is significantly governed by grain boundaries (GBs), a typical crystal defects inside, which often exhibit unique properties due to the structural and chemical inhomogeneity. Here, it is reported direct atomic scale evidence that oxygen vacancies formed in the GBs can modify the local surface oxygen dynamics in CeO2, a key material for fuel cells. The atomic structures and oxygen vacancy concentrations in individual GBs are obtained by electron microscopy and theoretical cal
Crystalline interfaces in materials often govern the macroscopic functional properties owing to their complex structure and chemical inhomogeneity. For ionic crystals, however, such understanding has been precluded by the debatable local anion distribution across crystal interfaces. In this study, using yttria-stabilized zirconia as a model material, the oxygen vacancy distribution across individual grain boundaries was directly quantified by atomic-resolution scanning transmission electron micr
This paper presents a new optimization method for dynamic design of planar linkage with clearances at joints. The general consideration is to optimize the mass distribution of links to reduce the change of joint forces. The mass, the center position of mass and the moment of inertia the moving links are taken as the optimizing variables. The objective functions are taken as the changes of the amplitude and direction of the joint forces and they are minimized. The optimized result shows that the
In oxide materials, the presence of dislocations often strongly affects the properties of thin film and multilayer devices. Although it was reported that ionic conduction can be enhanced by introducing dislocations in ionic conductors, the underlying mechanism of such enhancement remains unclear. Here we analyzed the ionic conduction enhancement in an yttria-stabilized zirconia (YSZ) single edge dislocation from a structural point of view, using atomic resolution scanning transmission electron m
The atomic structure of a Σ3 [110]/(111) grain boundary in CeO2 was studied by scanning transmission electron microscopy, electron energy loss spectroscopy, and the first-principles calculations. It was revealed that this grain boundary does not promote the formation of oxygen vacancies and keeps oxygen stoichiometry, which is different from that of Σ5 CeO2 grain boundary studied previously [H. Hojo, T. Mizoguchi, H. Ohta, S. D. Findlay, N. Shibata, T. Yamamoto, and Y. Ikuhara, Nano Lett. 10, 46
