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Solar water splitting using photoelectrochemical cells (PECs) has emerged as one of the most promising routes to produce hydrogen as a clean and renewable fuel source. Among various semiconductors that have been considered as photoelectrodes for use in PECs, oxide-based photoanodes are particularly attractive because of their stability in aqueous media in addition to inexpensive and facile processing compared to other types of semiconductors. However, they typically suffer from poor charge carri

A fine-tuned organic working solution that synergistically combines auto- and photocatalysis achieves one of the highest solar-to-chemical conversion efficiencies of up to 1.1% to coproduce H 2 O 2 and aldehyde under simulated sunlight.

5-Hydroxymethylfurfural (HMF), which can be derived from lignocellulosic biomass, is an important platform molecule that can be used to produce valuable biofuels and polymeric materials. Electrochemical reduction of HMF is of great interest as it uses water as the hydrogen source and achieves desired reduction reactions at room temperature and ambient pressure. Hydrogenation and hydrogenolysis are two important reactions for reductive HMF conversion. Therefore, elucidating key characteristics of

Abstract Ni phosphides and NiCo alloys are extensively explored for their remarkable efficiency in biomass alcohol oxidations, yet the underlying mechanisms remain inadequately understood. This study thoroughly elucidates the roles of Ni, Co, and P in improving the catalytic performance of Ni‐Co‐P catalysts for the electrochemical conversion of 5‐hydroxymethylfurfural (HMF) to 2,5‐furandicarboxylic acid (FDCA), a promising biomass‐derived building block replacing terephthalic acid. Phosphorizati

As CuInGa-based chalcopyrite photocathodes suffer from poor hydrogen evolution activity, n-type overlayers and hydrogen evolution catalysts (HECs) need to be deposited on the film surface to drive surface band bending and reduce the overpotential for the hydrogen evolution reaction (HER). Here, we present a Cu(In,Ga)(S,Se)2 (CIGSSe) photocathode with grown-in CuxS HECs enabling solar water splitting without the deposition of additional n-type overlayers and HECs. The controlled two-step chalcoge

A core-shell metal oxide photocatalyst providing energy states for visible light absorption and efficient electron–hole separation has been reported and proven to be very efficient for solar-to-fuel conversion of carbon dioxide. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporti

A multi metal (M: Fe, Co, and Ni)-doped rectangular ZnO nanocrystal (r-ZnO:M) was synthesised using nanocrystalline metal-organic framework-5 (n-MOF-5). After calcination in air, M-inserted n-MOF-5 led to r-ZnO:M of the wurtzite crystal structure with a small amount (<1%) of spinel ZnM2O4 phase. The inserted metal atoms of r-ZnO:M, replacing the Zn atoms of the wurtzite ZnO structure, were well-dispersed throughout the nanocrystal. Density functional theory calculations not only confirm the stru

5-hydroxymethylfurfural oxidation reaction (HMFOR) has been considered as promising anodic reaction alternating oxygen evolution reaction (OER). The introduction of Fe into layered nickel hydroxide has been effective strategy to enhance performance of OER as well as HMFOR. However, considering that HMFOR and OER are competitive with each other, it is hardly understandable how Fe simultaneously enhances both reactions. Herein, we provide an insight toward the role of Fe in the layered Ni(OH)2 in

Herein, we report a facile method for synthesizing graphitic carbon domains of thin island shapes on the surfaces of titania nanotubes, which were prepared by using hydrothermal and pyrolytic treatments with glucose. The faster decay time of the solar-driven electrons and the lower charge transport resistance on carbon domains as compared to those in the case of bare titania nanotubes serve to increase the solar-to-hydrogen conversion rate.

The removal of nitric oxide (NO), which is an aggregation agent for fine dust that causes air pollution, from exhaust gas has been considered an important treatment in the context of environmental conservation. Herein, we propose a sustainable electrochemical NO removal system based on the reversible Fe2+/Fe3+-ethylenediamine tetraacetic acid (EDTA) redox reaction, which enables continuous NO capture and storage at ambient temperature without the addition of any sacrificial agents. We have desig

H₂-driven microbial electrosynthesis (MES) is an emerging bioelectrochemical technology that enables the production of complex compounds from CO₂. Although the performance of microbial fermentation in the MES system is closely related to the H₂ production rate, high-performing metallic H₂-evolving catalysts (HEC) generate cytotoxic H₂O₂ and metal cations from undesirable side reactions, severely damaging microorganisms. Herein, a

This paper shows how much the size of groove and ridge, which were fabricated on the silicon wafer, affected on the hydrophobicity of the grooved surface without chemical treatments and with chemical treatment such as self-assembled monolayers (SAMs) of organic silane. Furthermore, the contact angles (CAs) of water droplet on specimens were measured and compared with theoretical CAs of droplet in Cassie-Baxter state. The experimental results indicated that the specimen with the extensive groove

Electrochemical oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA) is a promising pathway for chemical synthesis, yet challenges remain in catalyst efficiency, product purity, and scalable implementation. In this study, NiV layered double hydroxide (LDH) was explored as a highly effective catalyst for electrochemical HMF oxidation. The incorporation of V significantly stabilized the Ni3+ state, promoted strong HMF adsorption, and accelerated the oxidation of key inte