백재훈 교수

Tuning the metal-support interaction of supported metal catalysts has been found to be the most effective approach to modulating electronic structure and improving catalytic performance. But practical understanding of the charge transfer mechanism at the electronic level of catalysis process has remained elusive. Here, it is reported that ruthenium (Ru) nanoparticles can self-accommodate into Fe₃ O₄ and carbon support (Ru-Fe₃ O₄ /C) through the electro

Water electrolysis to produce hydrogen (H₂) using renewable energy is one of the most promising candidates for realizing carbon neutrality, but its reaction kinetics is hindered by sluggish anodic oxygen evolution reaction (OER). Ruthenium (Ru) in its high-valence state (oxide) provides one of the most active OER sites and is less costly, but thermodynamically unstable. The strong interaction between Ru nanoparticles (NPs) and nickel hydroxide (Ni(OH)₂) is leveraged to dire

Abstract Fluorinated carbon materials (FCMs) have received significant attention, because of their exceptional stability, which is associated with the strong C‐F bonding, the strongest among carbon single bonds. However, the fluorination of carbon materials requires extremely toxic and moisture‐sensitive reagents, which makes it inapplicable for practical uses. Here, a straightforward and relatively safe method are reported for the scalable synthesis of FCMs, by mechanochemical depolymerization

Developing efficient and cost-effective electrocatalysts to replace expensive carbon-supported platinum nanoparticles for the alkaline hydrogen evolution reaction remains an important challenge. Recently, an innovative catalyst, composed of ruthenium single atoms (Ru₁) integrated with small Ru nanoclusters (Ru_NC), has attracted considerable attention from the scientific community. However, because of its complexity, this catalyst remains a topic of some debate. Here, a meth

Ammonia (NH₃) has emerged as a promising hydrogen (H₂) carrier thanks to its high hydrogen content (17.6 wt %) and easy liquification. However, conventional NH₃ cracking requires high temperatures (400-600 °C) and additional gas separation processes, increasing the regeneration cost of high-purity H₂. Here, we develop a mechanochemical NH₃-silicon (Si) reaction that enables high-purity H₂ production under mild conditions (50.0 °C)

Platinum (Pt) nanoparticles are considered to be the most efficient catalyst for acidic hydrogen evolution reaction (HER). However, they are expensive and unstable, because of agglomeration and Ostwald ripening. It is critically necessary for developing a better catalytic support to stabilize the Pt nanoparticles at low loading amounts. One efficient route to improving both catalytic activity and durability is metal catalysts stably anchored on heteroatom functionalized carbon supports via their

This paper presents an advanced pulse width modulation (PWM) method with cross-correlation-based digital signal processing for electric vehicle (EV) application. The algorithm is designed to adaptively apply PWM techniques depending on motor operating conditions: space vector PWM (SVPWM) method in the high total harmonic distortion (THD) condition and the discontinuous PWM (DPWM) method in the low harmonics operating condition of an EV motor. The phase current of EV motor changes by the torque c

Proton exchange membrane water electrolysis (PEMWE) is a promising strategy for sustainable hydrogen production, but its application is limited by the high cost and instability of catalysts under acidic operation conditions. Here, the study reports group VA element-doped graphitic nanoplatelets (XGnPs; X = N, P, or Sb) as effective supports to enhance both the activity and durability of electrocatalysts. The resulting platinum (Pt) nanoparticles on XGnPs (Pt@XGnPs) catalysts exhibit improved cha

Nitrous oxide (N₂O) is one of the top three greenhouse gases, together with carbon dioxide and methane, but it is stable enough not to be easily decomposed under thermocatalytic conditions, even at high temperature (445 °C). Herein, an efficient N₂O decomposition method is reported using nickel oxide catalyst under mechanochemical conditions operated near ambient temperature. The mechanochemical N₂O decomposition method exhibited a rapid reaction rate of 1761.3 m

Abstract The practical application of lithium metal batteries (LMBs) in carbonate‐based electrolytes is hindered by uncontrolled lithium (Li) deposition behavior. Here, a calcium fluoride (CaF 2 ) functionalized polyethylene (PE) separator (CF‐PE) is developed to spatially rearrange the inorganic components at the Li anode interface. A spontaneous cation exchange reaction between CaF 2 and detrimental lithium carbonate (Li 2 CO 3 ) generates a high modulus lithium fluoride (LiF) layer on the sur

Efficient sodium ion storage in graphite is as yet unattainable, because of the thermodynamic instability of sodium ion intercalates-graphite compounds. In this work, sodium fluorozirconate (Na₃ZrF₇, SFZ) functionalized graphite (SFZ-G) is designed and prepared by the in situ mechanochemical silicon (Si) replacement of sodium fluorosilicate (Na₂SiF₆, SFS) and functionalization of graphite at the same time. During the mechanochemical process, the atomic