서울대학교 · Engineering
강주김 교수의 연구실은 고효율 유기발광다이오드(OLED)의 핵심 요소인 발광체의 전자적·구조적 특성과 방향성에 중점을 두고 있으며, 특히 이리듐 및 플라티넘 기반 인광 발광체의 수직/수평 방향성 분포 제어와 효율적 에너지 전달 메커니즘을 연구하고 있습니다. Exciplex 형성 공호스트 시스템을 활용해 고출력, 저전압, 저효율 떨어짐을 동시에 구현한 OLED 기술을 개발하고 있으며, 이는 외부 양자효율 38.8%에 이르는 세계 최고 수준의 성능을 달성했습니다. 또한, 발광체의 분자 구조와 전이 이완 메커니즘 간의 상관관계를 X선 회절 및 양자화학 계산을 통해 규명함으로써, 설계 기반의 발광 소재 개발에 기여하고 있습니다.
표시된 성과는 수집된 데이터 기준으로 산출되며, 일부 차이가 있을 수 있습니다.
Abstract High‐efficiency phosphorescent organic light‐emitting diodes (OLEDs) doped with Ir(ppy) 2 (acac) [bis(2‐phenylpyridine)iridium(III)‐acetylacetonate] in an exciplex forming co‐host have been optically analyzed. This emitter has a preferred orientation with the horizontal to vertical dipole ratio of 0.77:0.23 as compared to 0.67:0.33 in the isotropic case. Theoretical analysis based on the orientation factor ( Θ , the ratio of the horizontal dipoles to total dipoles) and the photoluminesc
Abstract Phosphorescent organic light‐emitting diodes (OLEDs) with ultimate efficiency in terms of the external quantum efficiency (EQE), driving voltage, and efficiency roll‐off are reported, making use of an exciplex‐forming co‐host. This exciplex‐forming co‐host system enables efficient singlet and triplet energy transfers from the host exciplex to the phosphorescent dopant because the singlet and triplet energies of the exciplex are almost identical. In addition, the system has low probabili
It has been known for decades that the emitting dipole orientation (EDO) of emitting dyes influences the outcoupling efficiency of organic light-emitting diodes (OLEDs). However, the EDO of dopants, especially phosphorescent dopants, has been studied less than that of neat films and polymer emitting layers (EMLs) due to the lack of an apparent driving force for aligning the dopants in amorphous host films. Recently, however, even globular-shaped Ir complexes have been reported to have a preferre
Ancillary ligands in heteroleptic iridium complexes significantly influence the orientation of the transition dipole moments. Ir(ppy)3, a homoleptic iridium complex, exhibits isotropic dipole orientation, whereas the heteroleptic Ir complexes of Ir(ppy)2tmd show a highly preferred dipole orientation (78%) in the horizontal direction. In addition, we demonstrate an unprecedented highly efficient green OLED exhibiting an EQE of 32.3% and a power efficiency of 142.5 lm/W by using an emitter with hi
The exciplex forming co‐host with phosphorescent dopant system has potential to realize highly efficient phosphorescent organic light emitting didoes (PhOLEDs). However, the exciplex forming co‐host for blue phosphorescent OLEDs has been rarely introduced because of higher triplet level of the blue dopant than green and red dopants. In this work, a novel exciplex forming co‐host with high triplet energy level is developed by mixing a phosphine oxide based electron transporting material, PO‐T2T,
Organic light-emitting diodes with external quantum efficiency of 38.8% are realized using a Pt-based thin-film emitting layer with photoluminescence quantum yield of 96% and transition dipole ratio of 93%. The emitting dipole orientation of the thin films fabricated using Pt complexes is investigated and the structural relationship between X-ray structural analysis and the structures in thin films are discussed based on quantum chemical calculations.
Abstract An exciplex forming co‐host is introduced in order to fabricate orange organic light‐emitting diodes (OLEDs) with high efficiency, low driving voltage and an extremely low efficiency roll‐off, by the co‐doping of green and red emitting phosphorescence dyes in the host. The orange OLEDs achieves a low turn‐on voltage of 2.4 V, which is equivalent to the triplet energy gap of the phosphorescent‐green emitting dopant, and a very high external quantum efficiency (EQE) of 25.0%. Moreover, th
Bimolecular and trap‐assisted recombination mechanisms are investigated in small molecule‐based phosphorescent organic light emitting diodes (PhOLEDs) using the current−voltage−luminance characteristics in the diffusion current region, along with transient electroluminescence and capacitance measurements. Two different PhOLEDs, one with a single host, 4,4′‐Bis(carbazol‐9‐yl)biphenyl, and the other with an exciplex‐forming co‐host, are studied. Trap‐assisted recombination with a large number of t
White OLEDs with high efficiency and high color stability are developed by using high energy level dopants. The white OLEDs showed high external quantum efficiency of 11.7% and remarkable color stability with the variation of CIE chromaticity coordinates less than (0.02, 0.01) between 10 cd m−2 and 5000 cd m−2. Moreover roll-off of efficiency was low and the CRI value was over 87. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2089/2008/
Tandem white organic light-emitting diodes (WOLEDs) using horizontally oriented phosphorescent dyes in an exciplex-forming co-host are presented, along with an orange OLED. A high external quantum efficiency of 32% is achieved for the orange OLED at 1000 cd m(-2) and the tandem WOLEDs exhibit a high maximum EQE of 54.3% (PE of 63 lm W(-1)).
A 2,7-functionalized pyrene-based emitter for highly efficient OLEDs has been developed. It offers an exceptional deep blue photoluminescence (CIE: <italic>x</italic> = 0.16, <italic>y</italic> = 0.024) and good external quantum efficiency (EQE) of 3.1% when employed in a guest–host system OLED.
The molecular alignment of platinum( II ) octaethyl porphyrin (PtOEP) crystals evaporated on KBr (see atomic force microscopy image, Figure) can be readily changed from perpendicular to parallel by changing the substrate temperature. The field‐effect mobility of transisitors prepared using epitaxially grown PtOEP films aligned perpendicularly to a substrate is 100 times higher than that of those of parallel alignment.
Abstract The rate‐limiting step of charge generation in charge‐generation units (CGUs) composed of a p‐doped hole‐transporting layer (p‐HTL), 1,4,5,8,9,11‐hexaazatriphenylene hexacarbonitrile (HATCN) and n‐doped electron‐transporting layer (n‐ETL), where 1,1‐bis‐(4‐bis(4‐methyl‐phenyl)‐amino‐phenyl)‐cyclohexane (TAPC) was used as the HTL is reported. Energy level alignment determined by the capacitance–voltage ( C – V ) measurements and the current density–voltage characteristics of the structur
Iridium complexes containing cyclometalated 2-cyclohexenylpyridine derivatives with rigid and bulky cyclohexene units are synthesized, and found to be highly efficient materials in EL devices (see figure). Devices based on these iridium complexes emit yellowish- green light with the very high external quantum efficiency of 18.7%.
