권지언 교수

Recently, organic fluorescent molecules harnessing the excited-state intramolecular proton transfer (ESIPT) process are drawing great attention due to their unique photophysical properties which facilitate novel optoelectronic applications. After a brief introduction to the ESIPT process and related photo-physical properties, molecular design strategies towards tailored emission are discussed in relation to their theoretical aspects. Subsequently, recent studies on advanced ESIPT molecules and t

A full-color molecular pixel system is realized for the first time using simple mixtures composed of RGB-emitting excited-state intramolecular proton transfer (ESIPT) dyes, each of which has delicately tailored Stokes shift and independent emission capability completely free from energy transfer crosstalk between them. It is demonstrated that the whole range of emission colors enclosed within the RGB color triangle on the CIE 1931 diagram is predictable and conveniently reproducible from the RGB

A new fluorescent zinc sensor (HNBO-DPA) consisting of 2-(2'-hydroxy-3'-naphthyl)benzoxazole (HNBO) chromophore and a di(2-picolyl)amine (DPA) metal chelator has been prepared and examined for zinc bioimaging. The probe exhibits zinc-induced fluorescence turn-on without any spectral shifts. Its crystal structure reveals that HNBO-DPA binds a zinc ion in a pentacoordinative fashion through the DPA and HNBO moieties. Steady-state photophysical studies establish zinc-induced deprotonation of the HN

Negligible structural reorganization of phenoxazine leads to superior rate capability and a narrow voltage plateau of a lithium–organic battery.

Triptycene bearing three benzoquinone moieties in a rigid 3-D tripod structure is capable of utilizing five-electron redox reactions that can provide a large capacity and high energy density in Li-ion cells.

Abstract Organic electrode materials hold great potential due to their cost‐efficiency, eco‐friendliness, and possibly high theoretical capacity. Nevertheless, most organic cathode materials exhibit a trade‐off relationship between the specific capacity and the voltage, failing to deliver high energy density. Herein, it is shown that the trade‐off can be mitigated by utilizing the multi‐redox capability of p‐type electrodes, which can significantly increase the specific capacity within a high‐vo

Because of the limitations of conventional metal-oxide-based electrodes, studies on organic redox-active materials as alternative electrodes for secondary batteries are emerging. However, reported organic electrode materials are still limited to a few kinds of organic redox groups. Therefore, the development of new redox-active groups for high-performance electrode materials is indispensable. Here, we evaluate s-tetrazine derivatives as a new electrode material in Li-ion batteries and study thei

Herein, we tune the redox potential of 3,6-diphenyl-1,2,4,5-tetrazine (DPT) by introducing various electron-donating/withdrawing groups (methoxy, t-butyl, H, F, and trifluoromethyl) into its two peripheral benzene rings for use as electrode material in a Li-ion cell. By both the theoretical DFT calculations and the practical cyclic voltammetry (CV) measurements, it is shown that the redox potentials (E_1/2) of the 1,2,4,5-tetrazines (s-tetrazines) have a strong correlation with the Ham