Kibum Kang 교수

Nanowires can serve as three-dimensional platforms at the nanometer scale for highly efficient chemical energy storage and conversion vehicles, such as fuel cells and secondary batteries. Here we report a coin-type Si nanowire (NW) half-cell Li-ion battery showing the Li capacity of approximately 4000 mAh/g, which nearly approaches the theoretical limit of 4200 mAh/g, with very high Coulombic efficiency of up to 98%. Concomitantly, we provide direct evidence of reversible phase transitions in th

We report amorphous-Si nanowire shell anodes, supported by NiSixnanowire cores, by catalyst-free two-step SiH4 chemical vapor deposition, where the metallic core acts as a mechanical supporter and a kinetically unlimited charge supplier. We have achieved highly reversible capacitance of over 3000 mAh g−1 even at a 2C rate, with stable cyclic retention which stems from the altered electrochemical reactions with relatively small volume expansion routes by a kinetic effect.

Abstract Transition metal dichalcogenides (TMDs) have attracted significant interest as gas‐sensing materials due to their unique crystal structure and surface. However, there are still issues when it comes to expanding the types of sensing gases for the TMD gas sensors. To extend gas‐sensing selectivity for the TMD gas sensors in this study, a monolayer (ML) 2D metal–organic framework (MOF) is introduced on top of the PtSe 2 gas sensor, thereby tuning the major sensing analyte of PtSe 2 from NO

We report a controllably reproducible and spontaneous growth of single-crystalline NiSix nanowires using NiOx/Ni seed layers during SiH4 chemical vapor deposition (CVD). We provide evidence that upon the reactions of SiH4 (vapor)-Ni seed layers (solid), the presence of the NiOx overlayer on Ni seed layers plays the key role to promote the spontaneous one-dimensional growth of NiSix single crystals without employing catalytic nanocrystals. Specifically, the spontaneous nanowire formation on the N

Ge nanowires are grown on Cu−Ni bulk alloys without the preparation of well-defined metal catalysts at the nanometer scale employing GeH4 precursor. GeH4 precursor selectively and catalytically decomposes into Cu within the Ni−Cu matrix and forms Cu3Ge nanocrystals in a self-organized manner. Subsequently, the decomposed Ge precipitates out from these Cu3Ge nanocrystals to crystallize into Ge nanowires.

Electric field driven reversible phase transitions in two-dimensional (2D) materials are appealing for their potential in switching applications. Here, we introduce potassium intercalated MnO₂ as an exemplary case. We demonstrate the synthesis of large-area single-crystal layered MnO₂ via chemical vapor deposition as thin as 5 nm. These crystals are spontaneously intercalated by potassium ions during the synthesis. We showed that the charge transport in 2D K-MnO₂