정광섭 교수

Colloidal quantum dot (CQD) photovoltaics offer a promising approach to harvest the near-IR region of the solar spectrum, where half of the sun's power reaching the earth resides. High external quantum efficiencies have been obtained in the visible region in lead chalcogenide CQD photovoltaics. However, the corresponding efficiencies for band gap radiation in the near-infrared lag behind because the thickness of CQD photovoltaic layers from which charge carriers can be extracted is limited by sh

HgS nanocrystals show a strong mid-infrared absorption and a bleach of the near-infrared band edge, both tunable in energy and reversibly controlled by exposure to solution ions under ambient conditions. The same effects are obtained by applying a reducing electrochemical potential, confirming that the mid-infrared absorption is the intraband transition of the quantum dot. This is the first time that stable carriers are present in the quantum state of strongly confined quantum dot in ambient con

Steady-state intraband transition, which is a promising electronic transition of a colloidal quantum dot along with the band-gap transition, had been a long-standing challenge. The steady-state intraband transition occurring between discrete electronic states in the conduction band of a colloidal nanocrystal has been reported only from mercury chalcogenide nanocrystals for the past few years. Concerns about the toxicity of the mercury compound necessitate a new nontoxic system exhibiting a stead

Mid-infrared intraband photoluminescence is observed from CdSe and CdS colloidal quantum dots (CQDs) and core/shell systems when excited by a visible laser. The CQDs show more intraband photoluminescence with dodecanethiol than with other ligands. Core/shells show an increase of the intraband photoluminescence with increasing shell thickness. The detected emission is restricted to below 2900 cm(-1), bounded by the C-H vibrational modes of the organic ligands. Upon photoexcitation in air for all

The tunable bandgap energy has been recognized as a prominent feature of the colloidal semiconductor nanocrystal, also called the colloidal quantum dot (CQD). Due to the broken degeneracy caused by the quantum confinement effect, the electronic states of the conduction band (CB) are separated by a few hundred meV. The electronic transition occurring in the conduction band is called the intraband transition and has been regarded as a fast electron relaxation process that cannot be readily observe

An increase in the carrier density of semiconductor nanocrystals can gradually change the origin of the optical property from the excitonic transition to the localized surface plasmon resonances. Here, we present the evolution of the electronic transition of self-doped Ag₂Se colloidal quantum dots, from the intraband transition to the localized surface plasmon resonances along with a splitting of the intraband transition (1P_e-1S_e). The minimum fwhm of the split i

Molecules affect the electronic properties of many emerging materials, ranging from organic thin film transistors and light emitting diodes for flexible displays to colloidal quantum dots (CQDs) used in solution processed photovoltaics and photodetectors. For example, the interactions of conjugated molecules not only influence morphological and charge transport properties of organic photovoltaic (OPV) materials, but they also determine the primary photophysical events leading to charge generatio

Demands on nontoxic nanomaterials in the short-wavelength infrared (SWIR) have rapidly grown over the past decade. Here, we present the nonstoichiometric silver chalcogenide nanocrystals of Ag_<i>x</i>Te (<i>x</i> > 2) and Ag₂Te/Ag₂S CQDs with a tunable bandgap across the SWIR region. When the atomic percent of the metal and chalcogenide elements are varied, the emission frequency of the excitonic peak is successfully extended to 2.7 μm. Surprisingly, the Ag<sub><

The infrared quantum plasmon resonance (IR QPR) of nanocrystals (NCs) exhibits the combined properties of classical and quantum mechanics, potentially overcoming the limitations of conventional optical features. However, research on the development of localized surface plasmon resonance (LSPR) from colloidal quantum dots has stagnated, owing to the challenge of increasing the carrier density of semiconductor NCs. Herein, we present the mid-IR QPR of a self-doped Ag₂Se NC with an excep

Solution-processable perovskite quantum dots are considered as promising optical materials for light-emitting optoelectronics. Light-emitting field-effect transistors (LEFETs) that can be operated under a relatively lower potential with a high energy conversion efficiency are yet to be realized with perovskite quantum dots. Here, we present the CsPbBr₃ quantum dot-based LEFET. Surprisingly, unipolar transport characteristics with strong electroluminescence were observed at the interfa

In search of heavy metal-free mid-IR active colloidal materials, self-doped silver selenide colloidal quantum dots (CQDs) can be an alternative offering tunable mid-IR wavelength with a narrow bandwidth. One of the challenges in the study of the intraband transition is developing a method to widen the intraband transition energy range as well as reducing the toxicity of the materials. Here, we present Ag_<i>x</i>Se (<i>x</i> > 2) CQDs exhibiting an intraband transition up to 0.39 eV, p

Tellurium has been of great interest in physics, chemistry, material science, and more recently in nanoscience. However, information on the photoluminescence of Te crystals, crucial in understanding the material, has never been disclosed. Here, we present photoluminescence and lasing for the Te bulk crystal and microcrystals. Photoluminescence of Te bulk solid crystal was observed at 3.75 μm in the midwavelength infrared (MWIR) region, matching the theoretically predicted value well. With increa