名古屋大学 · Materials Science
Shude Liu 교수의 연구실은 에너지 저장 소재 분야에 초점을 맞추고 있으며, 주로 아연 이온 배터리와 칼륨 이온 배터리의 고성능 카디오드 재료 개발을 핵심 연구 방향으로 삼고 있습니다. 특히 바나듐 기반 물질과 스파인 구조를 가진 cobaltite 계열의 나노소재를 설계하여 이온의 삽입·탈리의 거동을 최적화하고, 전기화학적 안정성과 사이클 수명을 향상시키는 데 주력하고 있습니다. 또한, 이종 나노구조의 합성 및 이온이동 메커니즘에 대한 기초 연구를 통해 차세대 고에너지 밀도 에너지 저장 장치의 실현 가능성을 탐색하고 있습니다.
표시된 성과는 수집된 데이터 기준으로 산출되며, 일부 차이가 있을 수 있습니다.
Abstract Aqueous zinc‐ion batteries (AZIBs) have attracted considerable attention as promising next‐generation power sources because of the abundance, low cost, eco‐friendliness, and high security of Zn resources. Recently, vanadium‐based materials as cathodes in AZIBs have gained interest owing to their rich electrochemical interaction with Zn 2+ and high theoretical capacity. However, existing AZIBs are still far from meeting commercial requirements. This article summarizes recent advances in
Flower-like copper cobaltite (CuCo2O4) nanosheets anchored on graphite paper have been synthesized using a facile hydrothermal method followed by a postannealing treatment. Supercapacitor electrodes employing CuCo2O4 nanosheets exhibit an enhanced capacitance of 1131 F g(-1) at a current density of 1 A g(-1) compared with previously reported supercapacitor electrodes. The CuCo2O4 electrode delivers a specific capacitance of up to 409 F g(-1) at a current density of as high as 50 A g(-1), and a g
With increasing demand for grid-scale energy storage, potassium-ion batteries (PIBs) have emerged as promising complements or alternatives to commercial lithium-ion batteries owing to the low cost, natural abundance of potassium resources, the low standard reduction potential of potassium, and fascinating K<sup>+</sup> transport kinetics in the electrolyte. However, the low energy density and unstable cycle life of cathode materials hamper their practical application. Therefore, cathode material
Rational assembly and hetero-growth of hybrid structures consisting of multiple components with distinctive features are a promising and challenging strategy to develop materials for energy storage applications.
Cation substitution is a promising strategy for modulating the structural properties and optimizing the electrochemical performance of spinel cobalt oxide (Co<sub>3</sub>O<sub>4</sub>); however, the underlying mechanism of this action induced by different cation substitutions has not yet been clearly addressed.
Cobaltite systems with spinel structures are promising cathode materials for next-generation high-performance electrochemical capacitors because of their high electrochemical stability.
Potassium ion energy storage devices are competitive candidates for grid-scale energy storage applications owing to the abundancy and cost-effectiveness of potassium (K) resources, the low standard redox potential of K/K<sup>+</sup>, and the high ionic conductivity in K-salt-containing electrolytes. However, the sluggish reaction dynamics and poor structural instability of battery-type anodes caused by the insertion/extraction of large K<sup>+</sup> ions inhibit the full potential of K ion energ
Exploring efficient strategies to overcome the performance constraints of oxygen evolution reaction (OER) electrocatalysts is vital for electrocatalytic applications such as H<sub>2</sub>O splitting, CO<sub>2</sub> reduction, N<sub>2</sub> reduction, <i>etc</i>. Herein, tunable, wide-range strain engineering of spinel oxides, such as NiFe<sub>2</sub>O<sub>4</sub>, is proposed to enhance the OER activity. The lattice strain is regulated by interfacial thermal mismatch during the bonding process b
Aqueous Zn-ion batteries (AZIBs) attract intensive attention owing to their environmental friendliness, cost-effectiveness, innate safety, and high specific capacity. However, the practical applications of AZIBs are hindered by several adverse phenomena, including corrosion, Zn dendrites, and hydrogen evolution. Herein, a Zn anode decorated with a 3D porous-structured Na<sub>3</sub> V<sub>2</sub> (PO4)<sub>3</sub> (NVP@Zn) is obtained, where the NVP reconstruct the electrolyte/anode interface. T
Flexible quasi-/all-solid-state supercapacitors have elicited scientific attention to fulfill the explosive demand for portable and wearable electronic devices. However, the use of electrode materials faces several challenges, such as intrinsically slow kinetics and volume change upon cycling, which impede the energy output and electrochemical stability. This study presents well-aligned molybdenum dioxide@nitrogen-doped carbon (MoO<sub>2</sub>@NC) and copper cobalt sulfide (CuCo<sub>2</sub>S<sub
Sodium- and potassium-ion (Na-/K-ion) hybrid capacitors are promising electrochemical energy storage systems that are more cost-effective than corresponding lithium-based alternatives. Their hybrid configuration integrates a battery-type anode and a capacitor-type cathode and affords high energy density, high power density, and good cycling stability. However, the primary issue encountered in Na-/K-ion hybrid capacitors is a lack of reliable anodes because of the sluggish reaction kinetics of la
This review provides a comprehensive overview detailing the advancements in desolvation strategies pertaining to aqueous zinc-ion batteries (AZIBs) performances, addressing the applications and working mechanisms of desolvation strategies in AZIBs.