Taeseup Song 교수

Silicon is a promising candidate for electrodes in lithium ion batteries due to its large theoretical energy density. Poor capacity retention, caused by pulverization of Si during cycling, frustrates its practical application. We have developed a nanostructured form of silicon, consisting of arrays of sealed, tubular geometries that is capable of accommodating large volume changes associated with lithiation in battery applications. Such electrodes exhibit high initial Coulombic efficiencies (i.e

Problems related to tremendous volume changes associated with cycling and the low electron conductivity and ion diffusivity of Si represent major obstacles to its use in high-capacity anodes for lithium ion batteries. We have developed a group IVA based nanotube heterostructure array, consisting of a high-capacity Si inner layer and a highly conductive Ge outer layer, to yield both favorable mechanics and kinetics in battery applications. This type of Si/Ge double-layered nanotube array electrod

The development of efficient and stable catalyst systems with low-cost, abundant, and non-toxic materials is the primary demand for electrochemical water oxidation. A unique method is reported for the syntheses of metal hydroxide carbonate templated Prussian blue analogues (PBAs) on carbon cloth and their outstanding water oxidation activities in alkaline medium. The best water oxidation activity is obtained with cobalt hydroxide carbonate templated t-Co^II -Co^III with an ov

A key issue with Na-ion batteries is the development of active materials with stable electrochemical reversibility through the understanding of their sodium storage mechanisms. We report a sodium storage mechanism and properties of a new anode material, digenite Cu_1.8S, based on its crystallographic study. It is revealed that copper sulfides (Cu _xS) can have metal-rich formulas ( x ≥ 1.6), due to the unique oxidation state of +1 found in group 11 elements. These phases enab

The electrocatalytic performance of transition metal sulfide (TMS)–graphene composites has been simply regarded as the results of high conductivity and the large surface/volume ratio. However, unavoidable factors such as degree of oxidation of TMSs have been hardly considered for the origin of this catalytic activity of TMS–graphene composites. To accomplish the reliable application of TMS-based electrocatalytic materials, a clear understanding of the thermodynamic stability of TMS and effects o

Graphene oxide quantum dots (GOQDs) are usually prepared using expensive carbon precursors such as carbon nanotubes (CNT) or graphene under the strong acidic condition, which requires an additional purifying process. Here, we first develop a facile pulsed laser ablation in liquid (PLAL) technique for preparing GOQDs using earth-abundant and low-cost coal as a precursor. Only ethanol and coal are used to produce GOQDs with excellent optical properties. The prepared GOQDs exhibit excellent optoele

It has recently been demonstrated that the OER activity of transition metal sulfides (TMSs) could be enhanced by the introduction of a thin amorphous layer on a pristine surface.

Strain relaxation in semiconductor heterostructures generally occurs through the motion of dislocations that generates misfit dislocations above a critical thickness. However, majority of the threading dislocations in GaN-related materials have no driving force to glide, and those with a driving force are kinetically impeded even at a temperature of 1000 °C. In spite of this, the strain in InxGa1−xN∕GaN epilayers grown on c-plane sapphire substrates was observed to decrease as the InxGa1−xN laye

LiFePO₄ emerges as a viable alternative to cobalt-containing cathodes, such as Li[Ni_{1-<i>x</i>-<i>y</i>} Mn _<i>x</i> Co _<i>y</i> ]O₂ and Li[Ni_{1-<i>x</i>-<i>y</i>} Co _<i>x</i> Al _<i>y</i> ]O₂. As Fe is abundant in nature, LiFePO₄ is a low-cost material. Moreover, stable structure of LiFePO₄ imparts long service life and thermal stability. However, the practical implementation of