성균관대학교 · Energy
Uk Sim 교수의 연구실은 탄소 기반 전기촉매 및 나노소재를 중심으로 태양광 및 전기화학적 에너지 변환 기술을 연구하고 있습니다. 특히, 고효율 수소 생산을 위한 전기화학적 수소발생(HER), 암모니아 산화 반응(AOR), 이산화탄소 환원 반응(CO2RR) 등에서 뛰어난 촉매 성능을 보이는 니켈 기반 나노구조물과 질소 도핑된 탄소 기반 전기촉매를 개발하고 있습니다. 또한, 광전해수소생산을 위한 그래핀 및 나노와이어 기반 광촉매 시스템의 최적화와 생체적합성 있는 나노입자를 활용한 광열 치료 응용도 함께 진행하고 있습니다.
표시된 성과는 수집된 데이터 기준으로 산출되며, 일부 차이가 있을 수 있습니다.
A high CO<sub>2</sub> to CO electroreduction rate exceeding 300 mA cm<sup>−2</sup> was achieved with single atom nickel and nitrogen doped three-dimensional porous carbon electrocatalysts.
N-doped graphene quantum sheets decorated on a Si nanowire photocathode electrode serve as an efficient electrocatalyst for photoelectrochemical hydrogen production.
Carbon-based catalysts have been attracting attention in renewable energy technologies due to the low cost and high stability, but their insufficient activity is still a challenging issue. Here, we suggest that monolayer graphene can be used as a catalyst for solar-driven hydrogen evolution reaction on Si-photocathodes, and its catalytic activity is boosted by plasma treatment in N2-ambient. The plasma treatment induces abundant defects and the incorporation of nitrogen atoms in the graphene str
This review summarizes recent advances in synthesis strategies, structural engineering, and unique properties of transition metal nitrides, along with the critical discussion on electrode designs for supercapacitors to meet commercial standards.
Since carbon dots (CDs) exhibit excellent biocompatibility, low cytotoxicity, near-infrared (NIR) absorbance, and superior photostability, many types of CDs are considered as powerful candidates for photothermal therapy (PTT) applications. However, the development of a desirable CD is still difficult due to insufficient photothermal conversion, thus resulting in the use of high laser power densities at a high dose of CDs for the PTT effect. Herein, bioinspired sulfur-doped CDs (S-CDs) with stron
Ammonia, as an efficient hydrogen carrier, is emerging as an alternative energy resource to replace fossil fuels in the carbon–neutral era. Hydrogen production by water electrolysis seeks a lower potential dependent anodic reaction to overcome its energy-inefficiency that originates from the high potential anodic oxygen evolution reaction (OER). In this work, nickel phosphide supported on nitrogen doped-carbon (Ni2P@N-C) was prepared by one-pot synthesis for the bifunctional activity of hydrogen
The electrochemical reduction of carbon dioxide (CO<sub>2</sub> ) to value-added products is a promising approach to reducing excess CO<sub>2</sub> in the atmosphere. However, the development of electrocatalysts for highly selective and efficient electrochemical CO<sub>2</sub> reduction has been challenging because protons are usually easier to reduce than CO<sub>2</sub> in an aqueous electrolyte. Recently, single-atom catalysts (SACs) have been suggested as candidate CO<sub>2</sub> reduction ca
Hydrogen production from solar power energy is an important energy and environmental issue. Silicon (Si) has been widely studied as a photocathode for hydrogen production from water splitting. In this study, the electrochemical behavior of a Si photocathode for water splitting is highly dependent on its nanostructure. The optimum nanostructure of a Si photocathode exhibits an enhanced photocurrent and a lower overpotential compared to the planar bulk Si. The limiting current density of nanostruc
Platinum is a key component of commercialized proton exchange membrane fuel cells (PEMFCs) to lower the energy cost of the sluggish oxygen reduction reaction (ORR) at the cathode. Beyond the significant advances in improving its initial activity, securing catalytic durability is the next challenge for the successful implementation of PEMFCs. Encapsulation of Pt nanoparticles (NPs) with thin carbon or silica layers has recently been highlighted as a promising strategy for alleviating Pt degradati
The unique physical and chemical properties of spinels have made them highly suitable electrocatalysts in oxygen evolution reaction and oxygen reduction reaction (OER & ORR). Zinc–air batteries (ZABs), which are safer and more cost-effective power sources than commercial lithium-ion batteries, hinge on ORR and OER. The slow kinetics of the air electrode reduce its high theoretical energy density and specific capacity, which limits its practical applications. Thus, tuning the performance of t
The vacuum deposition method requires high energy and temperature. Hydrophobic reduced graphene oxide (rGO) can be obtained by plasma-enhanced chemical vapor deposition under atmospheric pressure, which shows the hydrophobic surface property. Further, to compare the effect of hydrophobic and the hydrophilic nature of catalysts in the photoelectrochemical cell (PEC), the prepared rGO was additionally treated with plasma that attaches oxygen functional groups effectively to obtain hydrophilic grap