東北大学 · Engineering
Wei Li 교수의 연구실은 나노소재 및 전기화학 에너지 변환 기술 분야에서 활발한 연구를 수행하고 있습니다. 주요 연구 방향은 그래핀 및 복합 나노소재의 정밀 합성, 전이금속 기반 촉매(특히 산소 반응 촉매)의 원자 구조 제어 및 활성 메커니즘 규명입니다. 특히 Zn-공기 전지와 같은 고에너지 밀도 전지 시스템의 효율성 향상 및 지속 가능성 확보를 위한 재료 설계에 초점을 맞추고 있습니다.
표시된 성과는 수집된 데이터 기준으로 산출되며, 일부 차이가 있을 수 있습니다.
Abstract Synthesis of structurally controlled graphene materials is critical for realizing their practical applications. The electrochemical exfoliation of graphite has emerged as a simple method to produce graphene materials. This review examines research progress in the last 5 years, from 2015 to 2019. Graphene material synthesis methods generally have a trade‐off between increasing production yield and achieving better material property control. The synthesis conditions for synthesizing prist
Metal oxides of earth-abundant elements are promising electrocatalysts to overcome the sluggish oxygen evolution and oxygen reduction reaction (OER/ORR) in many electrochemical energy-conversion devices. However, it is difficult to control their catalytic activity precisely. Here, a general three-stage synthesis strategy is described to produce a family of hybrid materials comprising amorphous bimetallic oxide nanoparticles anchored on N-doped reduced graphene oxide with simultaneous control of
Metal–nitrogen–carbon (M–N–C) single-atom catalysts (SACs) show high catalytic activity for many important chemical reactions. However, an understanding of their intrinsic catalytic activity remains ambiguous because of the lack of well-defined atomic structure control in current M–N–C SACs. Here, we use covalent organic framework SACs with an identical metal coordination environment as model catalysts to elucidate the intrinsic catalytic activity of various metal centers in M–N–C SACs. A pH-uni
The century-old zinc-air (Zn-air) battery concept has been revived in the last decade due to its high theoretical energy density, environmental-friendliness, affordability, and safety. Particularly, electrically rechargeable Zn-air battery technologies are of great importance for bulk applications like electric vehicles, grid management, and portable electronic devices. Nevertheless, Zn-air batteries are still not competitive enough to realize widespread practical adoption because of issues in e
Mutations in the p53 and retinoblastoma (pRb) pathways associated with the use of tobacco and alcohol are common in squamous cell carcinoma (SCC) of the head and neck. Cell cycle proteins are also affected by human papillomavirus (HPV), which may also have an aetiological role in cancers at particular sites, most notably the tonsil. Attempts to identify prognostic molecular markers in head and neck cancers have met with conflicting results, but few studies have been undertaken with tumours of kn
Abstract Transition metal cobalt (oxy)hydroxides are promising catalyst candidates for the oxygen evolution reaction (OER). Their activity can be significantly enhanced by doping chromium; however, the optimal catalyst elemental composition is unknown, and the exact role of Cr remains elusive. Here, density functional theory (DFT) calculations and comprehensive catalyst characterization are combined to address these two questions. Guided by DFT calculations, a series of amorphous ternary Co‐iron
The rapid growth in silver nanoparticles (AgNPs) commercialization has increased environmental exposure, including aquatic ecosystem. It has been reported that the AgNPs have damaging effects on photosynthesis and induce oxidative stress, but the toxic mechanism of AgNPs is still a matter of debate. In the present study, on the model aquatic higher plant Spirodela polyrhiza, we found that AgNPs affect photosynthesis and significantly inhibit Photosystem II (PSII) maximum quantum yield (F<sub>v</
Abstract The aqueous Zn ion battery (ZIB) is a potentially sustainable energy storage device. However, its performance is still far from satisfactory. Herein, it is demonstrated that a branched sugar, dextran, widely used in eyedrop products to relieve irritated eyes, is a multifunctional and universal electrolyte additive to enable high‐performance ZIBs. Experimental and theoretical results reveal that dextran has four functions: forming a surface protective layer to minimize side reactions, fa
Two-dimensional covalent organic frameworks (2D-COFs) may serve as an emerging family of catalysts with well-defined atomic structures. However, the severe stacking of 2D nanosheets and large intrinsic bandgaps significantly impair their catalytic performance. Here, we report coaxial one-dimensional van der Waals heterostructures (1D vdWHs) comprised of a carbon nanotube (CNT) core and a thickness tunable thienothiophene-pyrene COF shell using a solution-based <i>in situ</i> wrapping method. Den
Nickel phosphide has a much higher catalytic activity for the hydrogen evolution reaction in strongly acidic and basic electrolytes.
Electrochemical splitting of water to produce oxygen (O<sub>2</sub>) and hydrogen (H<sub>2</sub>) through a cathodic hydrogen evolution reaction (HER) and an anodic oxygen evolution reaction (OER) is a promising green approach for sustainable energy supply. Here we demonstrated a porous nickel-copper phosphide (NiCuP) nano-foam as a bifunctional electrocatalyst for highly efficient total water splitting. Prepared from a bubble-templated electrodeposition method and subsequent low-temperature pho