大阪大学 · 工学
Fei Li教授の研究室は、高エントロピー酸化物をはじめとする新規機能材料の設計・合成・応用に注力しています。特に、高融点・高耐熱性を示す高エントロピーペロブスカイト型酸化物やUltra-High Temperature Ceramics(UHTC)の開発を通じて、宇宙用エンジンや核融合炉など極限環境下でも安定に働く材料の創出を目指しています。また、2次元高エントロピー水酸化物やスピンエルス型高エントロピー酸化物を用いたセンシング材料の開発も進め、環境ガス検出やエネルギー変換応用への展開を図っています。
Figures are computed from collected data and may differ slightly.
High-entropy pyrochlore-type structures based on rare-earth zirconates are successfully produced by conventional solid-state reaction method. Six rare-earth oxides (La2O3, Nd2O3, Sm2O3, Eu2O3, Gd2O3, and Y2O3) and ZrO2 are used as the raw powders. Five out of the six rare-earth oxides with equimolar ratio and ZrO2 are mixed and sintered at different temperatures for investigating the reaction process. The results demonstrate that the high-entropy pyrochlores (5RE1/5)2Zr2O7 have been formed after
Abstract Ultra-high temperature ceramics (UHTCs) are considered as a family of nonmetallic and inorganic materials that have melting point over 3000 °C. Chemically, nearly all UHTCs are borides, carbides, and nitrides of early transition metals (e.g., Zr, Hf, Nb, Ta). Within the last two decades, except for the great achievements in the densification, microstructure tailoring, and mechanical property improvements of UHTCs, many methods have been established for the preparation of porous UHTCs, a
This paper reports the simultaneous measurements of multiple flow parameters in a scramjet facility operating at a nominal Mach number of 2.5 using a sensing system based on tunable diode-laser absorption spectroscopy (TDLAS). The TDLAS system measures velocity, temperature, and water vapor partial pressure at three different locations of the scramjet: the inlet, the combustion region near the flame stabilization cavity, and the exit of the combustor. These measurements enable the determination
Low-dimensional high-entropy materials, such as nanoparticles and two-dimensional (2D) layers, have great potential for catalysis and energy applications. However, it is still challenging to synthesize 2D layered high-entropy materials through a bottom-up soft chemistry method, due to the difficulty of mixing and assembling multiple elements in 2D layers. Here, we report a simple polyol process for the synthesis of a series of 2D layered high-entropy transition metal (Co, Cr, Fe, Mn, Ni, and Zn)
Zn1−xYbxO (0 ≤ x ≤ 0.02) thin films have been prepared by inductively coupled plasma enhanced physical vapor deposition method. All the Yb-doped ZnO thin films show room-temperature ferromagnetism. The correlation between oxygen vacancy and magnetism in Yb-doped ZnO thin films is studied. It is found that Yb irons initially substitute for Zn sites when x ≤ 0.01 and then enter the interstitial sites of ZnO with increasing Yb concentration of x > 0.01. The ferromagnetism is induced by the c
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