北海道大学 · 材料科学
Hai Jun Cho教授の研究室では、酸化物半導体やコバルト酸化物を用いた機能性酸化物薄膜のエpitaxial成長と物性制御を柱としており、特に透明酸化物半導体における高移動度実現や、深紫外線透過電極としての応用に向けた材料設計が進められています。また、熱伝導率の低減を目的とした超格子構造を有する酸化物薄膜の開発や、欠陥工学を応用した物性制御の研究も展開しています。これらの研究は、次世代のエレクトロニクス・エナジー材料の開発に貢献するものです。
Figures are computed from collected data and may differ slightly.
Wide bandgap (Eg ∼ 3.1 eV) La-doped BaSnO3 (LBSO) has attracted increasing attention as one of the transparent oxide semiconductors since its bulk single crystal shows a high carrier mobility (∼320 cm2 V−1 s−1) with a high carrier concentration (∼1020 cm−3). For this reason, many researchers have fabricated LBSO epitaxial films thus far, but the obtainable carrier mobility is substantially low compared to that of single crystals due to the formation of the lattice/structural defects. Here we rep
La-doped SrSnO3 (LSSO) is known as one of the deep-ultraviolet (DUV)-transparent conducting oxides with an energy bandgap of similar to 4.6 eV. Since LSSO can be grown heteroepitaxially on more wide bandgap substrates such as MgO (E-g similar to 7.8 eV), LSSO is considered to be a good candidate for a DUV-transparent electrode. However, the electrical conductivity of LSSO films is below 1000 S cm(-1), most likely due to the low solubility of the La ion in the LSSO lattice. Here, we report that h
Abstract Layered cobalt oxides, A x CoO 2 (A = Li, Na, Ca, and Sr), are attracting attention as thermoelectric materials showing large thermoelectric figure of merit ZT = S 2 σTκ −1 ( S : thermopower, σ: electrical conductivity, T : absolute temperature, κ: thermal conductivity) at higher temperatures. Due to the layered structure, A x CoO 2 shows strong anisotropy in the thermoelectric properties; both S and σ are large along the layer though systematic study in κ is not reported thus far. Here
Transparent La-doped BaSnO${}_{3}$ (LBSO) is a promising optoelectronic material due to its excellent single-crystal electron transport properties. However, the mobility of LBSO thin films is much lower than single-crystal values. This is mainly attributed to threading dislocations, but they have not been enough to fully explain this phenomenon. Using transport properties and stoichiometry control, the authors investigate the mobility suppression in LBSO films in a broader perspective. The resul
Abstract Heat conduction in ceramics is attributed to phonon propagation, which can be strongly suppressed at boundaries. Usually, polycrystals show lower thermal conductivity (κ) than single crystals, as polycrystals contain many grain boundaries. For functional applications in thermal management technologies, ceramics with low thermal conductivity are required. While grain boundary engineering is effective for reducing κ, its utilization is limited by the fact that other functional properties
Wide bandgap (~3.1 eV) La-doped BaSnO3 (LBSO) has attracted increasing attention as one of the transparent oxide semiconductors since its bulk single crystal shows a high carrier mobility (~320 cm2 V-1 s-1) with a high carrier concentration (~10^20 cm-3). For this reason, many researchers have fabricated LBSO epitaxial films thus far, but the obtainable carrier mobility is substantially low compared to that of single crystals due to the formation of the lattice/structural defects. Here we report
Abstract Thin film transistors (TFT) with deep‐UV transparency are a promising component for next‐generation optoelectronics such as biosensors. Among several deep‐UV transparent oxide semiconductors, SrSnO 3 is an excellent candidate material owing to its wide band gap (≈4.6 eV) and rather high carrier electron mobility. Herein, fabrication and operation mechanism of the SrSnO 3 ‐TFT is shown. A metal–insulator‐semiconductor structure is fabricated on a 28 nm‐thick SrSnO 3 film. The resultant T
Abstract The interface between two materials can be expected to show exotic optical, electrical, and thermal transport properties due to the difference in chemical bonding and chemical potential. However, in conventional material systems, the volume fraction of the interface is small compared to bulk, and interfacial properties are thus difficult to utilize. In this regard, multilayered films are essential to increase the volume fraction of interfaces and functionalize their properties. Here it
La-doped SrSnO3 (LSSO) is known as one of the deep-ultraviolet (DUV)-transparent conducting oxides with an energy bandgap of ∼4.6 eV. Since LSSO can be grown heteroepitaxially on more wide bandgap substrates such as MgO (Eg ∼ 7.8 eV), LSSO is considered to be a good candidate for a DUV-transparent electrode. However, the electrical conductivity of LSSO films is below 1000 S cm−1, most likely due to the low solubility of the La ion in the LSSO lattice. Here, we report that high electrically condu
Open papers in the app to read, cite, and organize with AI.