한정우

Electrocatalysis undeniably offers noteworthy improvements to future energy conversion and storage technologies, such as fuel cells, water electrolyzers, and metal–air batteries.

With the need for more stable and active metal catalysts for dry reforming of methane, in situ grown nanoparticles using exsolution are a promising approach. However, in conventional exsolution, most nanoparticles remain underneath the surface because of the sluggish diffusion rate of cations. Here, we report the atomic layer deposition (ALD)-combined topotactic exsolution on La_0.6Sr_0.2Ti_0.85Ni_0.15O_3-δ toward developing active and durable ca

Single-atom nanozymes (SAzymes) are promising in next-generation nanozymes, nevertheless, how to rationally modulate the microenvironment of SAzymes with controllable multi-enzyme properties is still challenging. Herein, we systematically investigate the relationship between atomic configuration and multi-enzymatic performances. The constructed Mn_SA -N₃ -coordinated SAzymes (Mn_SA -N₃ -C) exhibits much more remarkable oxidase-, peroxidase-, and glutathi

Doping perovskite oxide with different cations is used to improve its electro-catalytic performance for various energy and environment devices. In this work, an activated lattice oxygen activity in Pr_0.4 Sr_0.6 Co_x Fe_0.9- _x Nb_0.1 O_3- _δ (PSCxFN, x = 0, 0.2, 0.7) thin film model system by B-site cation doping is reported. As Co doping level increases, PSCxFN thin films exhibit higher concentration of oxygen vaca

We use a combination of density functional theory (DFT) calculations and experimental approaches to explore the stability and electrocatalytic activity of a wide range of transition-metal single atoms on a TiC support. Our theoretical prediction that single atoms can be stabilized on the modified TiC surface is confirmed by experimental findings using them on a TiC support. The predicted activities where Pt and Au single atoms would be the best for hydrogen evolution and selective oxygen reducti

Abstract A catalyst active to carbon monoxide (CO) oxidation at low temperature is essential for environmental conservation, saving fuel and improvement of the quality of human life. Rational design of CO oxidation catalyst on the basis of comprehensive understanding of physicochemical properties of catalytic materials, rather than simply searching for the catalyst based on trial‐and‐error, is a promising approach to meet the increasingly stringent regulations. This review covers metal‐doped and

The recently reported fast oxygen reduction kinetics at the interface of (La,Sr)CoO3−δ (LSC113) and (La,Sr)2CoO4+δ (LSC214) phases opened up new questions for the potential role of dissimilar interfaces in advanced cathodes for solid oxide fuel cells (SOFCs). Using first-principles based calculations in the framework of density functional theory, we quantitatively probed the possible mechanisms that govern the oxygen reduction activity enhancement at this hetero-interface as a model system. Our

High-energy and long cycle lithium-sulfur (Li-S) pouch cells are limited by the insufficient capacities and stabilities of their cathodes under practical electrolyte/sulfur (E/S), electrolyte/capacity (E/C), and negative/positive (N/P) ratios. Herein, an advanced cathode comprising highly active Fe single-atom catalysts (SACs) is reported to form 320.2 W h kg^-1 multistacked Li-S pouch cells with total capacity of ≈1 A h level, satisfying low E/S (3.0), E/C (2.8), and N/P (2.3) ratios

Abstract Peroxidase‐mimicking nanozymes have been extensively studied, however, their application is limited by the requirement for an acidic pH. Herein, the development of Co‐doped mesoporous cerium oxide (Co‐m‐ceria) is reported, which operates optimally at a near‐neutral pH and exhibits a peroxidase‐like catalytic efficiency that is 600‐times higher than that of pristine m‐ceria. Density functional theory (DFT) calculations for the application of pristine and various metal‐doped m‐ceria in pe