Nagoya University · 化学工学
Sato教授の研究室は、ナノ材料を用いた次世代触媒の開発を柱としており、特にレアメタルの代替や触媒の耐久性向上に注力しています。60GHz帯のミリ波通信における電波伝搬の可視性向上や、アンモニアからの水素生成プロセスの常温起動技術の開発も進めています。また、白金を極限まで低減した合金触媒の設計とその電子状態制御による反応性向上の研究も展開しています。
Figures are computed from collected data and may differ slightly.
Millimeter-wave application systems such as indoor communication systems need direct connection between the base stations and terminals. Because human bodies may block the propagation-paths in the 60 GHz band in indoor environments, we have estimated the propagation-path visibility in office environments in which there is shadowing by human bodies. Although a lot of base stations or very tall terminals are needed to avoid shadowing by human bodies perfectly without base station diversity, divers
Rh is one of the most important noble metals for industrial applications. A major fraction of Rh is used as a catalyst for emission control in automotive catalytic converters because of its unparalleled activity toward NOx reduction. However, Rh is a rare and extremely expensive element; thus, the development of Rh alternative composed of abundant elements is desirable. Pd and Ru are located at the right and left of Rh in the periodic table, respectively, nevertheless this combination of element
Ammonia has received attention as a hydrogen carrier for energy use, and although ammonia decomposition can produce hydrogen at a high rate, there is currently no simple process for decomposing ammonia that is easily and rapidly initiated at any time without an input of external energy. Here, we report the discovery of a process for initiating and sustaining the production of hydrogen from ammonia without heating the catalyst externally. The oxidative decomposition of ammonia to produce hydrogen
In this paper, we define, for arithmetic schemes with semi-stable reduction, p-adic objects playing the roles of Tate twists in tale topology, and establish their fundamental properties.
Hydrogen is a promising clean energy source. In domestic polymer electrolyte fuel cell systems, hydrogen is produced by reforming of natural gas; however, the reformate contains carbon monoxide (CO) as a major impurity. This CO is removed from the reformate by a combination of the water-gas shift reaction and preferential oxidation of CO (PROX). Currently, Ru-based catalysts are the most common type of PROX catalyst; however, their durability against ammonia (NH<sub>3</sub>) as an impurity produ
There is interest in minimizing or eliminating the use of Pt in catalysts by replacing it with more widely abundant and cost-effective elements. The alloying of Pt with non-noble metals is a potential strategy for reducing Pt use because interactions between Pt and non-noble metals can modify the catalyst structure and electronic properties. Here, a γ-Al<sub>2</sub> O<sub>3</sub> -supported bimetallic catalyst [Pt(0.1)Co(1)/Al<sub>2</sub> O<sub>3</sub> ] was prepared which contained 0.1 wt % Pt
Nitrile hydrogenation over PdPt random alloy nanoparticles.
Ruthenium catalysts may allow for realization of renewable energy-based ammonia synthesis processes using mild reaction conditions (<400 °C, <10 MPa). However, ruthenium is relatively rare and therefore expensive. Here, we report a Co nanoparticle catalyst loaded on a basic Ba/La<sub>2</sub>O<sub>3</sub> support and prereduced at 700 °C (Co/Ba/La<sub>2</sub>O<sub>3</sub>_700red) that showed higher ammonia synthesis activity at 350 °C and 1.0-3.0 MPa than two benchmark Ru catalysts, Cs<sup>+</sup
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