Kimihisa Yamamoto

Recently, thermally activated delayed fluorescence (TADF) materials have received increasing attention as effective emitters for organic light-emitting diodes (OLEDs). However, most of them are usually employed as dopants in a host material. In this report, carbazole dendrimers with a triphenyl-s-triazine core are reported, which are the first solution-processable, non-doped, high-molecular-weight TADF materials. The dendrimers were obtained by a new and facile synthetic route using the tert-but

Among various approaches synthesizing metal nanoparticles and tiny clusters, a template method using dendrimers has significant advantages over other chemical approaches with respect to their synthetic precision and the scalability. A dendrimer of polydentate ligands assembles metal ions or salts into the interior allowing production of metal nanoparticles in the dendrimer. The dendrimer-encapsulated nanoparticles (DENs) exhibit unique and remarkable catalytic properties depending on the size an

Mix and more than match: Relative to the catalytic activity of pure Rh nanoparticles in a dendrimer cage, Rh/Fe bimetallic nanoparticles in dendrimers have improved catalytic activity towards the hydrogenation of olefins, and unlike Wilkinson catalyst could catalyze nitroarene hydrogenation (see scheme, G4=4th generation dendrimer).

The catalytic activity of alloy nanoparticles depends on the particle size and composition ratio of different metals. Alloy nanoparticles composed of Pd, Pt, and Au are widely used as catalysts for oxidation reactions. The catalytic activities of Pt and Au nanoparticles in oxidation reactions are known to increase as the particle size decreases and to increase on the metal-metal interface of alloy nanoparticles. Therefore, multimetallic nanoclusters (MNCs) around 1 nm in diameter have potential

Classical metal-based nanomaterials come in two prominent types: a mononuclear or multinuclear complex chemically stabilized by organic ligands or a nanoparticle (also called a nanorod, nanosheet, or nanocrystal) physically stabilized by inorganic or polymer supports. Over the last decade, a class of superatoms that lies between these categories of materials has attracted attention because their properties are dramatically different from those typically ascribed to their component elements. Typi

New solution processable and laminatable terminally modified carbazole-triazine thermally activated delayed fluorescence (TADF) dendrimers are reported. An OLED device with fully solution processed organic layers exhibited an external quantum efficiency of up to 9.4% at 100 cd m^-2.

A series of second-generation carbazole-benzophenone dendrimer substituted by several functional groups at terminal positions (subG2B) was investigated toward a thermally activated delayed fluorescence (TADF) emitter for nondoped emissive layer (EML) application in a solution-processed organic light-emitting diode (OLED). Substitution was found to dramatically alter the photophysical properties of the dendritic TADF emitters. The introduction of tert-butyl and phenyl group endows the subG2Bs wit

In an attempt to provide confirmation for the postulated mechanism of O2 reduction in vanadium-mediated oxidative polymerization of diphenyl disulfide, a series of divanadium complexes containing salen ligand (salen = N,N'-ethylenebis(salicylideneamine)) were prepared, characterized, and subjected to reactivity studies toward dioxygen. A divanadium(III, IV) complex, [(salen)VOV(salen)][I3] (II), was yielded both by treatments of solutions of [(salen)VOV(salen)][BF4]2 (I) in acetonitrile with exc

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAryl sulfide bond formation using the sulfoxide-acid system for synthesis of poly(p-phenylene sulfide) via poly(sulfonium cation) as a precursorKimihisa Yamamoto, Eiichi Shouji, Hiroyuki Nishide, and Eishun TsuchidaCite this: J. Am. Chem. Soc. 1993, 115, 13, 5819–5820Publication Date (Print):June 1, 1993Publication History Published online1 May 2002Published inissue 1 June 1993https://pubs.acs.org/doi/10.1021/ja00066a058https://doi.org/10.1021/ja00066a

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOxovanadium-catalyzed oxidative polymerization of diphenyl disulfides with oxygenKimihisa Yamamoto, Eishun Tsuchida, Hiroyuki Nishide, Mitsutoshi Jikei, and Kenichi OyaizuCite this: Macromolecules 1993, 26, 13, 3432–3437Publication Date (Print):June 1, 1993Publication History Published online1 May 2002Published inissue 1 June 1993https://pubs.acs.org/doi/10.1021/ma00065a029https://doi.org/10.1021/ma00065a029research-articleACS PublicationsRequest reuse

The phenylazomethine dendrimer generation 4 (TPP-DPA G4) and polyamidoamine dendrimer (PAMAM G4-OH) encapsulating rhodium nanocluster were found to be highly effective for olefin and nitroarene hydrogenations, affording high TOF (up to 17,520 h(-1)); the important feature of the nanocage catalyst is that substrates can pass through the branches of the protecting groups of nanoclusters without releasing nanoclusters from the dendrimer.

Abstract Recently, thermally activated delayed fluorescence (TADF) materials have received increasing attention as effective emitters for organic light‐emitting diodes (OLEDs). However, most of them are usually employed as dopants in a host material. In this report, carbazole dendrimers with a triphenyl‐s‐triazine core are reported, which are the first solution‐processable, non‐doped, high‐molecular‐weight TADF materials. The dendrimers were obtained by a new and facile synthetic route using the

TADF OLEDs with fully solution-processed organic-layers with all dendrimer emitting layers that exhibit 16.1% external quantum efficiency.