東北大学 · 化学工学
Kasai教授の研究室では、圧力・温度センシングに応用可能なフォトメトリックな塗料技術、特に圧力感受性ペイント(PSP)と温度感受性ペイント(TSP)の開発・評価を主軸としています。特に低圧環境下での高速応答性を有するPSPの開発や、PSP/TSPの同時測定における精度向上手法の確立が目立っています。また、高感度・低ノイズな画像強調技術を組み合わせた生体イメージング応用の研究も進められています。
Figures are computed from collected data and may differ slightly.
The characteristics of fast-response pressure-sensitive paints (PSPs) in low-pressure conditions were evaluated. Three representative porous binders were investigated: polymer-ceramic PSP (PC-PSP), anodized-aluminum PSP (AA-PSP), and thin-layer chromatography PSP (TLC-PSP). For each PSP, two types of luminophores, Pt(II) meso-tetra (pentafluorophenyl) porphine (PtTFPP) and tris(bathophenanthroline) ruthenium dichloride (Ru(dpp)3), were used as sensor molecules. Pressure sensitivities, temperatur
Abstract In this study, fast-response polymer-ceramic pressure-sensitive paints (PC-PSP) were developed and evaluated for pressure measurement under low-pressure conditions. The PC-PSP using poly[1-trimethylsilyl)-1-propyne] (poly(TMSP)), which has high oxygen permeability under low-pressure conditions, was developed in this study. The static and dynamic characteristics of the developed poly(TMSP)-based PC-PSP were evaluated in comparison with those of conventional poly(isobutyl methacrylate) (p
Abstract In this study, a new method that optimizes a measurement condition in a lifetime-based simultaneous measurement of a pressure-sensitive paint (PSP) and a temperature-sensitive paint (TSP) is proposed for the improvement of the accuracy of the pressure measurement. An optimal gate is selected based on a pressure measurement error when calculating the pressure and the temperature simultaneously from measurement values of a PSP and a TSP. A shot noise of a PSP, a temperature error, and a f
Abstract Two evaluation indexes were proposed to select the optimal PSP for unsteady pressure measurement from various PSPs with different pressure sensitivity and frequency response. An effective sensitivity coefficient calculated by pressure sensitivity and gain attenuation due to the response delay was proposed. Furthermore, an effective amount of intensity change was recommended, which takes into account the emission intensity and the effective sensitivity coefficient, because the magnitude
A temperature-sensitive paint (TSP) using a chameleon luminophore [ Tb 0 . 99 Eu 0 . 01 ( hfa ) 3 ( dpbp ) ] n is proposed. The chameleon luminophore was dispersed in isobutyl methacrylate polymer in a toluene solvent to fix it on a sample coupon. Temperature and pressure sensitivities of the chameleon luminophore-based TSP were measured using a spectrofluorophotometer. The emission for each wavelength was confirmed to be dependent on the temperature and pressure. The temperature and pressure se
To decrease both the intensity of the exciting light and the amount of sodium fluorescein, we attached a compact image intensifier incorporating a microchannel plate with a fundus photoscope and tried to record video-fluorescein angiography with low steady light. We preliminarily examined the relationships of exciting and emitted light intensity with various concentrations of sodium fluorescein. The strongest fluorescence was obtained with a concentration of 0.01 mg/ml solution of sodium fluores
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