東京大学 · 物理学・天文学
白石直人教授の研究室は、非平衡統計力学と量子熱力学の分野に焦点を当てており、特にマコフ過程に基づく非平衡系におけるエントロピー生成やエネルギー変換の制約を、情報幾何や変分原理の視点から理論的に解明しています。カーノー効率に到達できないことの普遍的根拠や、カタ拉的状態変換における熱力学的制約の完全な特徴付けなど、非平衡系の普遍的性質を解明する研究が特徴です。また、量子多体系のスカラ状態やマクスウェルの悪魔の統一的記述など、基礎的で普遍的な法則の解明を目指しています。
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For a general thermodynamic system described as a Markov process, we prove a general lower bound for dissipation in terms of the square of the heat current, thus establishing that nonvanishing current inevitably implies dissipation. This leads to a universal trade-off relation between efficiency and power, with which we rigorously prove that a heat engine with nonvanishing power never attains the Carnot efficiency. Our theory applies to systems arbitrarily far from equilibrium, and does not assu
We consider the speed limit for classical stochastic Markov processes with and without the local detailed balance condition. We find that, for both cases, a trade-off inequality exists between the speed of the state transformation and the entropy production. The dynamical activity is related to a time scale and plays a crucial role in the inequality. For the dynamics without the local detailed balance condition, we use the Hatano-Sasa entropy production instead of the standard entropy production
We establish a generalization of the fluctuation theorem for partially masked nonequilibrium dynamics. We introduce a partial entropy production with a subset of all possible transitions, and show that the partial entropy production satisfies the integral fluctuation theorem. Our result reveals the fundamental properties of a broad class of autonomous as well as nonautonomous nanomachines. In particular, our result gives a unified fluctuation theorem for both autonomous and nonautonomous Maxwell
Abstract We elucidate the deep connection between the PXP model, which is a standard model of quantum many-body scars, and the Affleck–Kennedy–Lieb–Tasaki (AKLT) Hamiltonian. Using the framework of embedded Hamiltonians, we establish the connection between the PXP Hamiltonian and the AKLT Hamiltonian, which clarifies the reason why the PXP Hamiltonian has nonthermal energy eigenstates similar to the AKLT state. Through this analysis, we find that the presence of such nonthermal energy eigenstate
The class of possible thermodynamic conversions can be extended by introducing an auxiliary system called catalyst, which assists in state conversion while its own state remains unchanged. We reveal a complete characterization of catalytic state conversion in quantum and single-shot thermodynamics by allowing an infinitesimal correlation between the system and the catalyst. Specifically, we prove that a single thermodynamic potential, which provides the necessary and sufficient condition for the
We establish that entropy production, which is crucial to the characterization of thermodynamic irreversibility, is obtained through a variational principle involving the Kulback-Leibler divergence. A simple application of this representation leads to an information-theoretical bound on entropy production in thermal relaxation processes; this is a stronger inequality than the conventional second law of thermodynamics. This bound is also interpreted as a constraint on the possible path of a therm
A long-standing open problem whether a heat engine with finite power achieves the Carnot efficiency is investgated. We rigorously prove a general trade-off inequality on thermodynamic efficiency and time interval of a cyclic process with quantum heat engines. In a first step, employing the Lieb-Robinson bound we establish an inequality on the change in a local observable caused by an operation far from support of the local observable. This inequality provides a rigorous characterization of the f
There have been two distinct formalisms of thermodynamics of information: One is the measurement-feedback formalism, which concerns bipartite systems with measurement and feedback processes, and the other is the information reservoir formalism, which considers bit sequences as a thermodynamic fuel. In this paper, we derive a second-law-like inequality by applying the measurement-feedback formalism to information reservoirs, which provides a stronger bound of extractable work than any other known
The investigation of thermalization in isolated quantum many-body systems has a long history, dating back to the time of developing statistical mechanics. Most quantum many-body systems in nature are considered to thermalize, while some never achieve thermal equilibrium. The central problem is to clarify whether a given system thermalizes, which has been addressed previously, but not resolved. Here, we show that this problem is undecidable. The resulting undecidability even applies when the syst
The maximum efficiency of autonomous engines with a finite chemical potential difference is investigated. We show that, without a particular type of singularity, autonomous engines cannot attain the Carnot efficiency. This singularity is realized in two ways: single particle transports and the thermodynamic limit. We demonstrate that both of these ways actually lead to the Carnot efficiency in concrete setups. Our results clearly illustrate that the singularity plays a crucial role in the maximu
The oscillation of fluctuation with two state observables is investigated. Following the idea of Ohga et al. [Phys. Rev. Lett. 131, 077101 (2023)10.1103/PhysRevLett.131.077101], we find that the fluctuation oscillation relative to their autocorrelations is bounded from above by the entropy production per characteristic maximum oscillation time. Our result applies to a variety of systems including Langevin systems, chemical reaction systems, and macroscopic systems. In addition, our bound consist
This paper is a Reply paper to the Comment paper by Mondaini et.al. [arXiv:1711.06279]. We first distinguish the diagonal and the off-diagonal eigenstate thermalization hypothesis (ETH) in each sector and in the whole Hilbert space, and then clarify their properties and their roles in thermalization. We argue that our formulation of the ETH in our letter is a standard and natural one in the context of thermalization, and that our results are qualitatively new and unexpected.
We investigate the bound on the speed of state transformation in the quantum systems that are coupled to general environments. We focus on the energy fluctuation of the target system and the coupling to the environment, and clarify the universal constraint on the state transformation deriving the general speed-limit inequality. This speed-limit inequality is applicable to any open systems including physical situations that have not been studied so far. We apply the inequality to the thermalizati
The condition for stationary engines to attain the Carnot efficiency in and beyond the linear response regime is investigated. We find that this condition for finite-size engines is significantly different from that for macroscopic engines in the thermodynamic limit. For the case of finite-size engines, the tight-coupling condition in the linear response regime directly implies the attainability of the Carnot efficiency beyond the linear response regime. As opposed to this, for the case of macro
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