Kyoto University · Materials Science
스스무 히타가와 교수의 연구실은 주로 다공성 코ordinative 폴리머(포화된 금속-유기 프레임워크)를 중심으로, 나노스케일의 공간 설계와 기능화를 통한 신소재 개발에 중점을 두고 있습니다. 특히, 나노스페이스 엔지니어링을 바탕으로 기체 흡착, 분리, 촉매 작용 등 다양한 응용 가능성을 지닌 다공성 구조를 합성하고 있으며, 유연한 프레임워크를 통해 기체의 가역적 흡착과 자기성 조절 등 동적 기능성을 실현합니다. 이는 에너지 저장, 환경 정화, 정밀 고분자 합성 등 응용 분야로 이어지는 핵심 기반 기술입니다.
Figures are computed from collected data and may differ slightly.
The chemistry of the coordination polymers has in recent years advanced extensively, affording various architectures, which are constructed from a variety of molecular building blocks with different interactions between them. The next challenge is the chemical and physical functionalization of these architectures, through the porous properties of the frameworks. This review concentrates on three aspects of coordination polymers: 1). the use of crystal engineering to construct porous frameworks f
In a decade, many porous coordination polymers have been synthesized, providing a variety of properties ranging from storage, separation, exchange of guests in their cavities, magnetism, conductivity and catalysis by their frameworks. In this tutorial review, we focus on the hydrogen bonding type arrangements for dynamic porous coordination polymers exhibiting elastic guest accommodations, in contrast to rigid three-dimensional (3-D) frameworks. Such dynamic porous properties induce highly-selec
Abstract Die Chemie der Koordinationspolymere hat sich in den vergangenen Jahren rasant entwickelt. Strukturen aus einer Vielzahl molekularer Bausteine mit unterschiedlichen Wechselwirkungen sind mittlerweile zugänglich. Die nächste Stufe ist die chemische und physikalische Funktionalisierung dieser Architekturen durch Einstellung ihrer Porositäten. Dieser Aufsatz konzentriert sich auf drei Aspekte von Koordinationspolymeren: 1) Anwendung von Kristall‐Engineering zum Aufbau poröser Gerüste aus K
Reversible adsorption of gases distinguishes the coordination polymers {[M2(4,4′-bpy)3(NO3)4](H2O)x}n (M = Co., x = 4; M = Ni, x = 4; M = Zn, x = 2), which are formed from M(NO3)2 and 4,4′-bipyridine in acetone/ethanol. The channeling cavities in the crystal frameworks (shown schematically on the right) have dimensions of about 3 × 6 Å along the a axis and about 3 × 3 Å along the b axis, and reversibly adsorb CH4, N2, and O2 in the pressure range of 1–36 atm without deformation of the crystal fr
Abstract Syntheses of new porous frameworks with specific pore size and type are of considerable interest for the appearance of zeolite-like functionalities. It is useful to take advantage of metal complex-assembled compounds because of designable frameworks, high microporosity, and flexible frameworks based on a variety of coordination geometries of metal centers and multifunctionality of bridging organic parts. Many recent reports show that the synthesis procedures are developing from serendip
Recent developments in polymerizations within the nanochannels of porous coordination polymers (PCPs) are covered in this tutorial review. The characteristic features of PCPs are regular structures, controllable channel sizes and shapes, a designable surface functionality, and flexible frameworks, which can be utilized for precision polymer synthesis and specific polymer confinement. This review discusses promising approaches to multiple controls of polymer structures, analysis systems for low-d
Stable tunable channels are formed by pillared-layer-type coordination networks [{Cu2(pzdc)2(L)}n] (pzdc = pyrazine-2,3-dicarboxylate; L = pyrazine, 4,4′-bipyridine, N-(4-pyridyl)isonicotinamide). Not only their channel sizes, shapes, and chemical environments are systematically built up by tuning the pillar ligands, but also the porosity is maintained in the absence of the included guest molecules. These compounds can adsorb methane, and the amount of gas adsorption is controllable by the type
Pore surface control of microporous coordination polymers is of great interest due to the potentially exciting functionalities it presents, such as highly selective separation, chemisorption, and novel catalysts and sensors. A discussion of our unique strategy aimed at surface engineering using metalloligands, i.e., introduction of coordinatively unsaturated metal centers, is presented.
In this Minireview, we discuss the fundamental chemistry of soft porous crystals (SPCs) by characterizing their common structural features and the resulting structural softness and transitions. In particular, we focus on the recently emerging properties based on metastable transitions and those arising from local dynamics. By comparing the resulting adsorption properties to those of commonly applied rigid adsorbents, we highlight the potential of SPCs to revolutionize adsorption-based technologi
Fabrication of hybrid MOF-on-MOF heteroarchitectures can create novel and multifunctional platforms to achieve desired properties. However, only MOFs with similar crystallographic parameters can be hybridized by the classical epitaxial growth method (EGM), which largely suppressed its applications. A general strategy, called internal extended growth method (IEGM), is demonstrated for the feasible assembly of MOFs with distinct crystallographic parameters in an MOF matrix. Various MOFs with diver
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