名古屋大学 · 工学
Yamamoto教授の研究室は、ポリマーのナノ構造形成と界面挙動に注目し、Soap-freeエマルジョン重合を基盤とした新規ナノ粒子の生成メカニズムを原子間力顕微鏡(AFM)を用いて分子スケールで解明しています。特に、反応温度やイニシエーターの種類が核生成や粒子成長に与える影響を精密に解析しており、粒子の表面電荷制御と界面接着性の向上を目的とした材料設計にも応用しています。炭素繊維と樹脂の界面結合強化や、酸化鉄含有コークスの反応性制御といった産業応用にもつながる革新的なプロセス開発が進められています。
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In recent years, the reduction of CO2 emissions and the stable supply of raw materials are two major issues for the steel industry. Low reducing agent operation in the blast furnace is required to reduce CO2 emissions in ironmaking. As a mean of realizing low reducing agent operation with using low-grade raw materials, ferro coke characterized by high coke reactivity is considered to be useful. Theoretical and experimental studies were carried out to verify the effect of the ferro coke usage on
To clarify the mechanism of the nucleation process in the soap-free polymerization of styrene in water, the polymerization process of styrene mainly at a temperature 46 degrees C was investigated on a molecular scale using an atomic force microscope (AFM) as well as a scanning electron microscope (SEM) and a dynamic light scattering apparatus (DLS). A cationic initiator was employed to make polymerized styrene adsorb electrostatically on the negatively charged mica plate with molecular-scale smo
Abstract The growth process of poly(isobutyl methacrylate) (PiBMA) particle prepared in soap-free polymerization using V-50 as an initiator was observed by atomic force microscopy (AFM) to clarify the growth mechanism. As a result, it was found that PiBMA particles were capable of growing by the adhesion of smaller particles, which generated freshly during the particle growth period, to their surfaces.
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