Yun Jeong Hwang

Oxygen–Cu (O–Cu) combination catalysts have recently achieved highly improved selectivity for ethylene production from the electrochemical CO2 reduction reaction (CO2RR). In this study, we developed anodized copper (AN-Cu) Cu(OH)2 catalysts by a simple electrochemical synthesis method and achieved ∼40% Faradaic efficiency for ethylene production, and high stability over 40 h. Notably, the initial reduction conditions applied to AN-Cu were critical to achieving selective and stable ethylene produ

There are currently great needs to develop low-cost inorganic materials that can efficiently perform solar water splitting as photoelectrolysis of water into hydrogen and oxygen has significant potential to provide clean energy. We investigate the Si/TiO(2) nanowire heterostructures to determine their potential for the photooxidation of water. We observed that highly dense Si/TiO(2) core/shell nanowire arrays enhanced the photocurrent by 2.5 times compared to planar Si/TiO(2) structure due to th

We report that the length and surface properties of TiO(2) nanowires can have a dramatic effect on their photoelectrochemical properties. To study the length dependence, rutile TiO(2) nanowires (0.28-1.8 μm) were grown on FTO substrates with different reaction times (50-180 min) using a hydrothermal method. Nanowires show an increase in photocurrent with length, and a maximum photocurrent of 0.73 mA/cm(2) was measured (1.5 V vs RHE) for 1.8 μm long nanowires under AM 1.5G simulated sunlight illu

Three-dimensional hierarchical nanostructures were synthesized by the halide chemical vapor deposition of InGaN nanowires on Si wire arrays. Single phase InGaN nanowires grew vertically on the sidewalls of Si wires and acted as a high surface area photoanode for solar water splitting. Electrochemical measurements showed that the photocurrent density with hierarchical Si/InGaN nanowire arrays increased by 5 times compared to the photocurrent density with InGaN nanowire arrays grown on planar Si (

Pd is one of the most effective catalysts for the electrochemical reduction of CO₂ to formate, a valuable liquid product, at low overpotential. However, the intrinsically high CO affinity of Pd makes the surface vulnerable to CO poisoning, resulting in rapid catalyst deactivation during CO₂ electroreduction. Herein, we utilize the interaction between metals and metal-organic frameworks to synthesize atomically dispersed Au on tensile-strained Pd nanoparticles showing signif

Nanostructure electrocatalysts are demonstrated for nitrate reduction reaction to ammonia production. Based on the understanding of material parameters and reaction intermediates, origins of the enhanced activity and perspectives are provided.

Metal–oxide interfaces provide a new opportunity to improve catalytic activity based on electronic and chemical interactions at the interface. Constructing a high density of interfaces is essential in maximizing synergistic interactions. Here, we demonstrate that Cu–ceria interfaces made by sintering nanocrystals facilitate C–C coupling reactions in electrochemical reduction of CO2. The Cu/ceria catalyst enhances the selectivity of ethylene and ethanol production with the suppression of H2 evolu

For practical applications, the deactivation processes of electrocatalysts in electrochemical CO₂ reduction reactions have to be addressed by studying recent advances such as exclusion of metal impurity effect, periodic electrochemical activation and active nanocatalyst design.

We demonstrate Ni–N/C is an effective electrocatalyst for the direct conversion of captured CO 2 in monoethanol amine-based aqueous absorbents showing high CO faradaic efficiency (78%) and its high selectivity is maintained in various amine solvents.

Electrochemical CO2 reduction is always accompanied by a competitive hydrogen evolution reaction as water is used as a hydrogen source. In addition to intrinsic activity control, geometrical factors of electrocatalysts such as their porous structure have been demonstrated to affect the reaction selectivity, but understanding its origin is still important. Herein, we demonstrate that reduced graphene oxide layers can effectively control the Faradaic efficiency for CO production of porous zinc nan