Hyeong‐U Kim

The metallic 1T phase of WS₂ (1T-WS₂ ), which boosts the charge transfer between the electron source and active edge sites, can be used as an efficient electrocatalyst for the hydrogen evolution reaction (HER). As the semiconductor 2H phase of WS₂ (2H-WS₂ ) is inherently stable, methods for synthesizing 1T-WS₂ are limited and complicated. Herein, a uniform wafer-scale 1T-WS₂ film is prepared using a plasma-enhanced chemical vapor

Two-dimensional (2D) transition metal dichalcogenides (TMDs) have attracted considerable attention owing to their synergetic effects with other 2D materials, such as graphene and hexagonal boron nitride, in TMD-based heterostructures. Therefore, it is important to understand the physical properties of TMD-TMD vertical heterostructures for their applications in next-generation electronic devices. However, the conventional synthesis process of TMD-TMD heterostructures has some critical limitations

A few-layered molybdenum disulfide (MoS2) thin film grown by plasma enhanced chemical vapor deposition was etched using a CF4 inductively coupled plasma, and the possibility of controlling the MoS2 layer thickness to a monolayer of MoS2 over a large area substrate was investigated. In addition, damage and contamination of the remaining MoS2 layer surface after etching and a possible method for film recovery was also investigated. The results from Raman spectroscopy and atomic force microscopy sh

This paper reports a biosensor based on a MoS₂-graphene (MG) composite that can measure the parathyroid hormone (PTH) concentration in serum samples from patients. The interaction between PTH and MG was analysed via an electrochemical sensing technique. The MG was functionalized using l-cysteine. Following this, PTH could be covalently immobilized on the MG sensing electrode. The properties of MG were evaluated using scanning electron microscopy, high-resolution transmission electron

Flexibile biosensors have a lot of applications in measuring the concentration of target bioanalytes. In combination with its flexibility, electrochemical sensors containing 2D materials have particular advantages such as enlarged area compatibility, transparency, and high scalability. A flexible biosensor was fabricated by direct synthesis of molybdenum disulfide (MoS₂) on a polyimide (PI) substrate, which can be used as the working electrode in electrochemistry platforms. The direct

Earth-abundant and inexpensive transition metal dichalcogenides (TMDCs) with existing polymorphisms (metallic 1T phase and semiconducting 2H phase) have been proposed as alternatives to noble metals (e.g., Pt, Ir, and Ru) to achieve an efficient hydrogen evolution reaction (HER). Although the 1T phase of TMDCs (1T-TMDCs) is essential as an HER catalyst, practical application in the HER has not been realized owing to the lack of any large-scale production of the 1T-TMDC and 1T/1T-TMDC heterostruc

Molybdenum oxide (MoO₃) has gained immense attention because of its high electron mobility, wide band gap, and excellent optical and catalytic properties. However, the synthesis of uniform and large-area MoO₃ is challenging. Here, we report the synthesis of wafer-scale α-MoO₃ by plasma oxidation of Mo deposited on Si/SiO₂. Mo was oxidized by O₂ plasma in a plasma enhanced chemical vapor deposition (PECVD) system at 150 °C. It was found that

Bulk layers of MoS₂ were synthesized <italic>in situ</italic> on a polymer substrate at low temperature for electrochemical biosensing.

Makers of point-of-care devices and wearable diagnostics prefer flexible electrodes over conventional electrodes. In this study, a flexible electrode platform is introduced with a WS₂ /graphene heterostructure on polyimide (WGP) for the concurrent and selective determination of dopamine and serotonin. The WGP is fabricated directly via plasma-enhanced chemical vapor deposition (PECVD) at 150 °C on a flexible polyimide substrate. Owing to the limitations of existing fabrication methods

Two-dimensional (2D) transition metal dichalcogenides (TMDs) have attracted attention as polymorphs depending on their phases (1T and 2H) when applying typical synthesis methods. The 2H phase is generally synthesised through chemical vapour deposition (CVD) on a wafer-scale at high temperatures, and many synthesis methods have been reported owing to their thermodynamic stability and semiconductor properties. By contrast, although the 1T phase is meta-stable with an octahedral coordination, there

Graphene has become to be the most spotlighted material because it has remarkable characteristics and advantages. Despite of these advantages, Graphene is difficult to apply to semiconductor devices because of low on/off ratio respectively with zero band-gap. However, since molybdenum disulfide (MoS 2 ) has the band gap of 1.96 eV in bulk state as well as the similar property with graphene, it can apply to semiconductor devices. Moreover single layer of MoS 2 has high mobility as 200cm 2 /v -1 s

The bifunctionality of chromism-integrated sensors and devices has been highlighted because of their reversibility, fast response, and visual indication. For example, one of the representative chromism electrochromic materials exhibits optical modulation under ion insertion/extraction by applying a potential. This operation mechanism can be integrated with various sensors (pressure, strain, biomolecules, gas, etc.) and devices (energy conversion/storage systems) as visual indicators for user-fri

Abstract The technique of plasma processing is beneficial for wafer cleaning and precision etching of integrated circuits and essential in manufacture of advanced semiconductor devices with unmatched perfection. Research on two‐dimensional (2D) materials, such as transition metal dichalcogenides(TMDs), offers a promising solution to the challenges in semiconductor miniaturization. TMDs, with their atomic layer thicknesses and silicon‐like bandgaps, can be integrated using existing plasma systems

Sampling and pre-detecting infectious diseases are effective ways of preventing them from widely spreading. Among the conventionally used sampling methods, cyclone-based air sampling is considered the simplest and most effective. In this study, we developed a new cyclone-type air sampler device by modifying the size and shape of a commercially available product, Coriolis µ (Bertin Technology). The newly built air sampler’s collection efficiency was measured using polystyrene particles by compari