Kiyonori Takahashi

Requirements for flexible electronic substrate are successfully accomplished by green nanocomposite film fabricated with two natural components: glycol-modified biomass lignin and Li⁺ montmorillonite clay. In addition to these major components, a cross-linking polymer between the lignin is incorporated into montmorillonite. Multilayer-assembled structure is formed due to stacking nature of high aspect montmorillonite, resulting in thermal durability up to 573 K, low thermal expansion,

CO2 and N2 gas adsorption/desorption properties of one-dimensional copper(II) polymers with paddle-wheel units [Cu(II)2(p-XBA)4(pyrazine)]∞ were successfully controlled through the tuning of interchain interactions by modification of para-substituent X groups on the benzoate (BA) ligands (X = Cl, Br, I, and OCH3). Although none of the four crystals had sufficient void space to integrate the crystallization solvents, gate-opening gas adsorption and desorption behaviors coupled with structural pha

To date, proton-conducting organic crystalline materials based on crown ethers have rarely been investigated.

Although the development of artificial molecular machines has garnered considerable attention in recent years, the construction of multifunctional solid-state molecular machines still faces several challenges. Herein, we report a supramolecular approach as an efficient strategy for building multifunctional trigger systems. In crystals composed of [Ni(dmit)2]− with a spin of S = 1/2 and supramolecular structures consisting of 4-aminopyridinium+ and benzo[18]crown-6, supramolecular cations with dy

m-Fluorobenzoate (m-FBA), 2,3-difluorobenzoate (2,3-F2BA), m-methylbenzoate (m-MBA), and m-chlorobenzoate (m-ClBA) were introduced into the Cu(II) binuclear unit as bridging ligands between two Cu(II) sites, which were further connected by an axial pyrazine (pz) ligand to form one-dimensional coordination polymers of [Cu(II)2(m-FBA)4(pz)]∞ (1), [Cu(II)2(2,3-F2BA)4(pz)]∞ (2), [Cu(II)2(m-MBA)4(pz)]∞ (3), and [Cu(II)2(m-ClBA)4(pz)]∞ (4), respectively. The parallel arrangements of one-dimensional (1

The pseudo-polyrotaxane structure of [(H-bpy⁺ )- (DB-24-crown-8)]_∞ (H-bpy⁺ = monoprotonated 4,4-bipyridinium; DB-24-crown-8 = dibenzo-24-crown-8) has been incorporated into the anion radical salt [Ni(dmit)₂ ]^- (dmit^2- = 1,3-dithiole-2-thione-4,5-dithiolate). (H-bpy⁺ )(DB-24-crown-8)[Ni(dmit)₂ ]^- crystallized as two polymorphs, crystals 1 and 2. Crystal 1 was found to have a lower density and looser

An alternative approach for achieving negative thermal expansion (NTE) in a molecular crystal of [Ni(dmit) 2 ] − salt with supramolecular cation composed of pyridazinium and dibenzo[24]crown-8. Deformation of supramolecular cation induces NTE and peculiar magnetic responses.

The crystal structure of a 1,6-bis(phenylethynyl)pyrene-based cyclophane was solved, and the mechanochromic luminescence was demonstrated.

Supramolecular cations, consisting of ethylammonium derivatives (X–CH₂CH₂–NH₃⁺) complexed with [18]crown-6, were incorporated into [Ni(dmit)₂]⁻ crystals in order to promote molecular motion.

Polar crystals exhibiting second-order harmonic generation (SHG) were designed by adjusting the intermolecular interactions of mononuclear Cu(ii) complexes in which one H2O, two pyridines (py), and two p-substituted benzoate (p-RBA) ligands (R = F, Cl, Br, I, CH3, and OCH3) were coordinated to a Cu(ii) ion, forming a penta-coordinated asymmetric [Cu(ii)(p-RBA)2(py)2(H2O)] mononuclear structure with a permanent dipole moment along the direction of the Cu-OH2 coordination axis. Each asymmetric [Cu

Using Na-encapsulated benzo[18]crown-6 (Na)(B18C6) as a counter cation, we successfully magnetically isolated a fluoride-bridging Dy dinuclear complex {[(PW₁₁O₃₉)Dy(H₂O)₂]₂F} (Dy₂POM) with lacunary Keggin ligands. (Na)(B18C6) formed two types of tetramers through C-H⋯O, π⋯π and C-H⋯π interactions, and each tetramer aligned in one dimension along the <i>c</i>-axis to form two types of channels. One channel was partially penetrated

Structural changes of the coordination polymer associated with gas adsorption (gate opening-type adsorption) can be linked to bulk physical properties such as magnetism, electrical conductivity, and dielectric properties. To enable real-space sensing applications, it is imperative to have a system where the selective adsorption of mixed gases can be correlated with physical properties. In this report, we demonstrate that a crystalline sample of one-dimensional (1D) coordination polymer exhibits