Dae Woo Kim

Laminated graphene oxide (GO) has promising use as a membrane because of its high permeance, chemical and mechanical stability, as well as the molecular sieving effect of its interlayers. However, the hydrophilic surface of GO, which is highly decorated with oxygen groups, easily induces delamination of stacked GO films in aqueous media, thereby limiting the practical application. To stabilize GO films in aqueous media, we functionalized a polymer support with branched polyethylene-imine (BPEI).

Abstract Layered two-dimensional materials can potentially be utilized for organic solvent nanofiltration (OSN) membrane fabrication owing to their precise molecular sieving by the interlayer structure and excellent stability in harsh conditions. Nevertheless, the extensive tortuosity of nanochannels and bulky solvent molecules impede rapid permeability. Herein, nanoporous graphene (NG) with a high density of sp 2 carbon domain was synthesized via sequential thermal pore activation of graphene o

Graphene oxide (GO) has been a prized material for fabricating separation membranes due to its immense potential and unique chemistry. Despite the academic focus on GO, the adoption of GO membranes in industry remains elusive. One of the challenges at hand for commercializing GO membranes lies with large-scale production techniques. Fortunately, emerging studies have acknowledged this issue, where many have aimed to deliver insights into scalable approaches showing potential to be employed in th

] were used as the sacrificial precursor. Successful phase conversion occurs as a result of the collaboration of low template stability and delayed delivery of 2-methylimidazole in weakly interacting solvents, particularly using acetone. When the ZIF-8 nanoplates with an average aspect ratio of 20 were shear aligned in the 6FDA-DAM polymer matrix by bar coating, the separation performance for propylene/propane far surpassed that of the previously reported mixed matrix and polymeric membranes, sh

Abstract Herein, we introduce a simple method to prepare hierarchical graphene with a tunable pore structure by activating graphene oxide (GO) with a two-step thermal annealing process. First, GO was treated at 600 °C by rapid thermal annealing in air, followed by subsequent thermal annealing in N 2 . The prepared graphene powder comprised abundant slit nanopores and micropores, showing a large specific surface area of 653.2 m 2 /g with a microporous surface area of 367.2 m 2 /g under optimized

In this study, reduced graphene oxide (rGO) and graphene oxide nanoribbons (GONRs) are used to fabricate a composite membrane that exhibits ultrafast water permeance (312.8 L m^-2 h^-1 bar^-1) and precise molecular separation (molecular weight cutoff: 269 Da), which surpass the upper bound of previously reported polymer and graphene-based nanofiltration membranes. As two-dimensional GONR exhibits a width on the scale of nanometers, its nanochannels can be enlarged w

MXenes have recently attracted significant interest owing to their outstanding properties and performance. However, their hydrophilic and metastable surfaces make most MXenes prone to oxidation, which can greatly degrade their properties and hinder their practical applications. Here, we enhanced the stability of Ti3C2Tx MXene films by coating a continuous zeolitic imidazolate framework-8 (ZIF-8) layer. The high-density oxygen functional groups of MXene, which are crucial for inducing the nucleat

Nanoporous graphene (size: <italic>ca.</italic> 3 nm, density: <italic>ca.</italic> 10¹⁵ m⁻²) can be synthesized in bulk by KOH activation of pre-oxidized graphite.

Large-scale fabrication of MXene films is in high demand for various applications, but it remains difficult to meet industrial requirements. In this study, we develop a slot-die coating method for the preparation of large-area MXene membranes. The technique allows the fabrication of continuous and scalable coatings with a rapid coating speed of 6 mm s^-1. The thickness can be readily controlled from the nanometer scale to the micrometer scale, and the alignment of the nanosheet is enha

The preparation of carbon materials based hydrogels and their viscoelastic properties are essential for their broad application and scale-up. However, existing studies are mainly focused on graphene derivatives and carbon nanotubes, and the behavior of graphene nanoribbon (GNR), a narrow strip of graphene, remains elusive. Herein, we demonstrate the concentration-driven gelation of oxidized GNR (graphene oxide nanoribbon, GONR) in aqueous solvents. Exfoliated individual GONRs sequentially assemb

Abstract Metal–organic frameworks (MOFs), which are highly ordered structures exhibiting sub‐nanometer porosity, possess significant potential for diverse gas applications. However, their inherent insulative properties limit their utility in electrochemical gas sensing. This investigation successfully modifies the electrical conductivity of zeolitic imidazolte framework‐8 (ZIF‐8) employing a straightforward surface oxidation methodology. A ZIF‐8 polycrystalline layer is applied on a wafer‐scale