이창하 교수
Chang‐Ha Lee
연세대학교 배터리공학과 · 공학
연구실 소개
이창하 교수의 연구실은 압력스위치흡착(PSA), 흡착 평형 및 동역학을 중심으로 한 기체분리 기술에 초점을 맞추고 있습니다. 주로 메탄, 수소, 이산화탄소 등의 분리에 효과적인 흡착제(제올라이트, 활성화탄, 탄소분자체 등)를 활용한 고도화된 분리 공정을 실험 및 이론적으로 연구하고 있으며, 특히 열역학적 비균일성과 농도 의존성 확산을 고려한 정밀한 모델링이 특징입니다. 이는 천연가스 정제, 수소 순도 향상, 폐기가스 재활용 등 실용적 응용을 목표로 합니다.
연구 현황
연구 성과 추이
표시된 성과는 수집된 데이터 기준으로 산출되며, 일부 차이가 있을 수 있습니다.
주요 논문
15The adsorption equilibria of CO 2 on zeolite 13X and zeolite X/activated carbon composite (Zeocarbon) were measured by a static volumetric method. The equilibrium experiments were conducted at (273.15, 293.15, 313.15, 333.15, and 353.15) K and at pressures up to 102.0 kPa for zeolite 13X and 99.7 kPa for Zeocarbon. The experimental data obtained were correlated by the Toth, UNILAN, and Sips models, which are generally used for microporous adsorbents such as zeolites and activated carbon. The iso
The adsorption equilibria of water vapor on zeolite 3A, zeolite 13X, and dealuminated Y zeolite (DAY) were measured using a volumetric method. Equilibrium experiments were conducted at 293.15, 303.15, and 313.15 K and at relative pressure ( P / P s ) up to 0.95. Experimental data were correlated using Aranovich–Donohue and Frenkel–Halsey–Hill models, using Langmuir, Toth, UNILAN, and Sips isotherms.
The adsorption equilibria of water vapor on Al 2 O 3, zeolite 13X, and a zeolite X/activated carbon composite (Zeocarbon) were measured by a static volumetric method. The equilibrium experiments were conducted at (293.2, 313.2, 333.1, and 353.1) K and pressures up to 2.1 kPa for Al 2 O 3 and 2.3 kPa for zeolite 13X and Zeocarbon, respectively. The experimental data obtained were correlated by the Aranovich and Donohue (A−D) and n -layer BET models.
A study on a two-bed six-step pressure swing adsorption (PSA) process using zeolite 5A was performed experimentally and theoretically for bulk separation of H 2 /CO and H 2 /CH 4 systems (70/30 vol %) as major components in coke oven gas. When the pressure is cycled between 1 and 11 atm at ambient temperatures, 70% H 2 in the feed could be concentrated to 99.99% in the product with a recovery of 75.87% in the H 2 /CO mixture and 80.38% in the H 2 /CH 4 mixture. The effects of adsorption pressure
Adsorption characteristics in a layered bed packed with activated carbon and zeolite 5A were studied experimentally and theoretically through the breakthrough experiments of binary (H 2 /CO, H 2 /CH 4, H 2 /CO 2 ), ternary (H 2 /CH 4 /CO), and five-component (H 2 /CH 4 /CO/N 2 /CO 2 ) systems. The effects of adsorption pressure, feed flow rate, and carbon-to-zeolite ratio on the breakthrough curve in a layered bed were observed. Breakthrough curves in all of the mixtures showed tailing due to te
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