문홍철 교수

Ion gels composed of a copolymer and a room temperature ionic liquid are versatile solid-state electrolytes with excellent features including high ionic conductivity, nonvolatility, easily tunable mechanical properties, good flexibility and solution processability. Ion gels can be functionalized by incorporating redox-active species such as electrochemiluminescent (ECL) luminophores or electrochromic (EC) dyes. Here, we enhance the functionality of EC gels for realizing multicolored EC devices (

The functionality of ion gels can be enhanced by incorporating different types of redox-active species. Here, we have expanded the functionality of ion gels composed of polystyrene- block -poly(methyl methacrylate)- block -polystyrene and 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide to include electrochromism by adding an electrochromic (EC) redox molecule, methyl viologen. Ferrocene was also added to the EC gel as an anodic species. The EC gel was inserted between two indium–ti

Ion gels comprising ABA triblock copolymers and ionic liquids have received much attention as functional materials in numerous applications, especially as gate dielectrics in organic transistors. Here we have expanded the functionality of ion gels by demonstrating low-voltage, flexible electrochemiluminescent (ECL) devices using patterned ion gels containing redox-active luminophores. The ECL devices consisted only of a 30 μm thick emissive gel and two electrodes and were fabricated on indium ti

Abstract The primary technology of next‐generation wearable electronics pursues the development of highly deformable and stable systems. Here, nonvolatile, highly transparent, and ultrastretchable ionic conductors based on polymeric gelators [poly(methyl methacrylate‐ ran ‐butyl acrylate), PMMA‐ r ‐PBA] and ionic liquids (IL) are proposed. A crucial strategy in the molecular design of polymer gelators is copolymerization of PMMA and IL‐insoluble low glass transition temperature ( T g ) polymers

Voltage-tunable multicolor electrochromic devices (ECDs) are fabricated based on flexible ion gels consisting of copolymers and ionic liquids as an electrolyte layer. Dimethyl ferrocene (dmFc) is incorporated into the gel, which serves as an anodic species. In this study, two electrochromic (EC) materials, monoheptyl viologen (MHV + ) and diheptyl viologen (DHV 2+ ), are employed and show significantly different EC behavior despite the similar chemical structure. Both MHV + - and DHV 2+ -contain

Herein, high-performance, reliable electrochromic supercapacitors (ECSs) are proposed based on tungsten trioxide (WO₃) and nickel oxide (NiO) films. To maximize device performance and stability, the stoichiometric balance between anode and cathode materials is controlled by carefully adjusting the thickness of the anodic NiO film while fixing the thickness of WO₃ to ∼660 nm. Then, a small amount (≤10 mol %) of metal (e.g., copper) is doped into the NiO film, improving the e

Integration of several functionalities into one isolated electrochemical body is necessary to realize compact and tiny smart electronics. Recently, two different technologies, electrochromic (EC) materials and energy storage, were combined to create a single system that supports and drives both functions simultaneously. In EC energy storage devices, the characteristic feature of EC materials, their optical modulation depending on the applied voltage, is used to visually identify the stored energ

Abstract Mesoporous metal oxides consisting of fully interconnected network structures with small pores (20–50 nm) have high surface areas and decreased ion intercalation distances, making them ideal for use in high-performance electrochromic supercapacitors (ECSs). Evaporation-induced self-assembly (EISA), which combines sol–gel chemistry and molecular self-assembly, is a powerful method for the fabrication of mesoporous metal oxides through a solution phase synthesis. Herein, we introduce ultr

Dual-function electrochromic supercapacitors (ECSs) that indicate their real-time charge capacity in color are fabricated using tungsten trioxide (WO₃) and Li-doped ion gels containing hydroquinone (HQ). The ECSs can simultaneously serve as either electrochromic devices or supercapacitors. The coloration/bleaching and charging/discharging characteristics are investigated between 0 and -1.5 V. At the optimal HQ concentration, large transmittance contrast (∼91%), high coloration efficie

Abstract Mechanically robust, highly ionic conductive gels based on a random copolymer of poly[styrene ‐ran‐ 1‐(4‐vinylbenzyl)‐3‐methylimidazolium hexafluorophosphate] (P[S ‐r‐ VBMI][PF 6 ]) and the ionic liquid 1‐ethyl‐3‐methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMI][TFSI]) are successfully prepared. The gels with either homo P[VBMI][PF 6 ] or conventional PS‐ block ‐poly(methyl methacrylate)‐ block ‐PS (SMS) show significant trade‐off between ionic conductivity and mechanical resil

The development of elastic ionic conductors offers opportunities to fabricate key wearable ionic components such as ionoskins that can perceive mechanical deformation. However, there is still plenty of room to overcome the trade-off between sensitivity and detectable range of previous systems and impart additional functionality. Here, we propose porous ion gels for high-performance, functional ionic sensory platforms. The porous ion gels can be effectively deformed by closing pores even with a s

Abstract Energy‐storing functional photovoltaics, which can simultaneously harvest and store solar energy, are proposed as promising next‐generation multifunction energy systems. For the extension of conventional organic photovoltaics (OPVs), electrochromic supercapacitors (ECSs) are monolithically integrated with semitransparent (ST) quaternary blend‐based OPVs (ST Q‐OPVs) to achieve compact, energy‐efficient storage with great aesthetic appeal. In particular, ST Q‐OPVs with low‐power‐consumpti

In this study, we propose low power consumption, all-in-one type electrochromic devices (ECDs) for effective heat shutters. Considering diffusion-controlled device operation, polymeric viologens (poly-viologens) are synthesized to lower the diffusivity of EC chromophores and to minimize self-bleaching. In comparison with devices based on mono-viologens corresponding to the monomer of poly-viologens, poly-viologen-containing ECDs exhibit advantages of lower coloration voltage (ca, -0.55 V) and hi

Low-voltage tungsten trioxide (WO₃)-based electrochromic devices (ECDs) are successfully demonstrated.