박홍이 교수
Hong-i Park
연세대학교 물리학과 · 재료과학
연구실 소개
박홍이 교수의 연구실은 주로 전이금속 이온 도핑을 통한 발광 재료, 특히 유럽산 염료를 활용한 고효율 백색 LED용 phosphor 개발에 초점을 맞추고 있습니다. 다양한 염기 earth 금속 실리케이트 및 칼코겐화합물 기반의 발광 물질에서 전자구조, 결정장 강도, 에너지 전달 메커니즘을 정밀하게 분석하며, Raman 스펙트로스코피와 EPR 측정을 통해 나노구조와 발광 메커니즘을 규명하고 있습니다. 특히, 색온도 제어와 높은 색재현성의 백색 발광 소자 실현을 위한 다성분 발광체 설계에 뛰어난 기여를 하고 있습니다.
연구 현황
연구 성과 추이
표시된 성과는 수집된 데이터 기준으로 산출되며, 일부 차이가 있을 수 있습니다.
주요 논문
15White-light-emitting diodes are fabricated by using 375nm emitting InGaN chip with Sr3MgSi2O8:Eu2+ (blue and yellow) or Sr3MgSi2O8:Eu2+, Mn2+ (blue, yellow, and red). At a color temperature of 5892K, the color coordinates are x=0.32, y=0.33, and the color rendering index is 84%; at a color temperature of 4494K, the color coordinates are x=0.35, y=0.33, and the color rendering index is 92%. The blue (470nm) and yellow (570nm) emission bands are originated from Eu2+ ions, while the red (680) emiss
The CaMgSi2O6:Eu2+, Mn2+ phosphors show three emission bands peaking at around 450nm (blue), 580nm (yellow), and 680nm (red). The blue band originates from the allowed f-d transition of Eu2+ ions on Ca sites. The yellow and red bands originate from the forbidden T14-A16 transition of Mn2+ ions on Mg2+ and Ca2+ sites, respectively. Electron paramagnetic resonance measurement demonstrates that Mn2+ ions occupy two different Ca2+ and Mg2+ sites. The mixtures of the green-poor CaMgSi2O6:Eu2+, Mn2+ a
Phonon modes of CdSe quantum dots in various glass matrices are investigated by Raman spectroscopy. The phonon energies are observed to be dependent on the host matrix as well as the quantum dot size. We have shown that the lattice contraction effect must be introduced to explain the observed differences of the phonon energies for CdSe quantum dots in the different glass matrices.
The photoluminescence (PL) spectra of Ba 3 MgSi 2 O 8 :Eu 2+ show one peak at 442 nm and two unresolved peaks at 505 nm. The 442 nm peak is attributed to the 4f→5d transition of the Eu 2+ ion doped in the Ba 2+ (I) site with a weak crystal field, while the 505 nm peak originates from Eu 2+ ions on the Ba 2+ (II) or the Ba 2+ (III) site with a strong crystal field. The PL spectra of the Sr 2 SiO 4 :Eu 2+ show two emission peaks at 470 nm and 560 nm. The emission intensity at 470 nm decreases with
Europium -doped alkaline earth orthosilicates , are studied as a phosphor for color-tunable white-light-emitting diode. With an increase of Ba ions in , the lattice constants increase, and the emission bands shift to higher energy in a systematic way. This blueshift behavior can be clarified by crystal field strength. Also, the lattice vibration energies from Raman spectra decrease with an increase of Ba ions in . The emission-quenching temperature dependence of the lattice vibration frequency i
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