정인환 교수

Abstract Herein, this study reports high‐efficiency, low‐temperature ZnO based planar perovskite solar cells (PSCs) with state‐of‐the‐art performance. They are achieved via a strategy that combines dual‐functional self‐assembled monolayer (SAM) modification of ZnO electron accepting layers (EALs) with sequential deposition of perovskite active layers. The SAMs, constructed from newly synthesized molecules with high dipole moments, act both as excellent surface wetting control layers and as elect

We have synthesized four types of cyclopentadithiophene (CDT)-based low-bandgap copolymers, poly[{4,4-bis(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b']dithiophene-2,6-diyl}-alt-(2,2'-bithiazole-5,5'-diyl)] (PehCDT-BT), poly[(4,4-dioctyl-4H-cyclopenta[2,1-b:3,4-b']dithiophene-2,6-diyl)-alt-(2,2'-bithiazole-5,5'-diyl)] (PocCDT-BT), poly[{4,4-bis(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b']dithiophene-2,6-diyl}-alt-{2,5-di(thiophen-2-yl)thiazolo[5,4-d]thiazole-5,5'-diyl}] (PehCDT-TZ), and poly[(4,4-diocty

Abstract We studied the thermoelectric properties of a diketopyrrolopyrrole-based semiconductor (PDPP3T) via a precisely tuned doping process using Iron (III) chloride. In particular, the doping states of PDPP3T film were linearly controlled depending on the dopant concentration. The outstanding Seebeck coefficient of PDPP3T assisted the excellent power factors (PFs) over 200 μW m −1 K −2 at the broad range of doping concentration (3–8 mM) and the maximum PF reached up to 276 μW m −1 K −2 , whic

New electron withdrawing monomers, thieno[2′,3′:5′,6′]pyrido[3,4- g ]thieno[3,2- c ]isoquinoline-5,11(4 H,10 H )-dione (TPTI) and fluorenedicyclopentathiophene dimalononitrile (CN), have been developed and used to form 12 alternating polymers having different monomer combinations: (a) weak donating monomer–strong accepting monomer, (b) weak accepting monomer–strong accepting monomer, (c) weak accepting monomer–weak accepting monomer, and (d) strong donating monomer–strong accepting monomer. It w

We studied fullerene-free organic solar cells using rhodanine-terminated BDT3TR and O-IDTBR.

Incorporation of a 2,5-difluorobenzene (F2B) moiety provides a unique structure with improved molecular ordering and blend morphology, giving a PCE reaching 5% using an F2B-containing acceptor (F2B-T2PDI) whereas using a counterpart acceptor gave only 3.63%.

Several electron accepting polymers having weak accepting–strong accepting (WA-SA) and strong accepting–strong accepting (SA-SA) monomer alternation were synthesized for studies of structure/property relationship in all-polymer solar cells. Two kinds of cyclic amide monomers, 4,10-bis(2-butyloctyl)-thieno[2′,3′:5,6]pyrido[3,4-g]thieno-[3,2- c ]isoquinoline-5,11-dione (TPTI) and 5,11-bis(2-butyloctyl)-thieno[2′,3′:4,5]pyrido[2,3-g]thieno[3,2- c ]quinoline-4,10-dione (TPTQ), were synthesized as we

Abstract We synthesized two fluorene‐based copolymers poly[(2,5‐bis(4‐hexylthiophen‐2‐yl)thiazolo[5,4‐day]thiazole‐5,5′‐diyl)‐alt‐(9,9′‐dioctylfluorene‐2,7‐diyl)] ( PF‐TTZT), and poly[(5,5′‐bis(4‐hexylthiophen‐2‐yl)‐2,2′‐bithiazole‐5,5′‐diyl)‐alt‐(9,9′‐dioctylfluorene‐2,7‐diyl)] (PF‐TBTT), which contain the electron‐withdrawing moieties, thiazolothiazole, and bithiazole, respectively. Through electrochemical studies, we found that these two polymers exhibit stable reversible oxidation and reduct

We developed a novel NIR-harvesting n-type porphyrin derivative, PDI–P_Zn–PDI, that shows a low bandgap of 1.27 eV. Panchromatic absorption was extended to the NIR area with a significantly low energy loss of 0.54 eV which led to promising photovoltaic performance.

While hole extraction is crucial for the external quantum efficiency of conventional n-i-p colloidal quantum dot (CQD) solar cells (CQDSCs), sulfur-passivated p-type CQDs (pCQDs) have been the best hole-transport material (HTM) to date. In this work, we developed organic π-conjugated polymers (π-CPs) that can achieve substantially improved HTM performance compared with conventional pCQDs. A weakly electron-withdrawing triisopropylsilylethynyl (TIPS) group was employed with a weak donor moiety, b

Although the combination of wide band gap polymer donors and narrow band gap small-molecule acceptors achieved state-of-the-art performance as bulk heterojunction (BHJ) active layers for organic solar cells, there have been only several of the wide band gap polymers that actually realized high-efficiency devices over >10%. Herein, we developed high-efficiency, low-energy-loss fullerene-free organic solar cells using a weakly crystalline wide band gap polymer donor, PBDTTPD-HT, and a nonfullerene

Organic photodetectors (OPDs) are attracting attention for use in flexible and portable electronic applications such as image sensors, remote sensing, optical communications, and medical sensors because of their strong photon responsivity in thin films over a broad range of wavelengths. In particular, the efficient photon-to-current conversion of OPDs under visible light allows their use in indirect X-ray detectors using scintillators to convert X-rays to visible light. The polymer poly(4,8-bis(

The susceptibility of porphyrin derivatives to light-harvesting and charge-transport operations have enabled these materials to be employed in solar cell applications. The potential of porphyrin derivatives as hole-transporting materials (HTMs) for perovskite solar cells (PSCs) has recently been demonstrated, but knowledge of the relationships between the porphyrin structure and device performance remains insufficient. In this work, a series of novel zinc porphyrin (PZn) derivatives has been dev

While the outstanding charge transport and sunlight-harvesting properties of porphyrin molecules are highly attractive as active materials for organic photovoltaic (OPV) devices, the development of n-type porphyrin-based electron acceptors has been challenging. In this work, we developed a high-performance porphyrin-based electron acceptor for OPVs by substitution of four naphthalene diimide (NDI) units at the perimeter of a Zn-porphyrin (P_Zn) core using ethyne linkage. Effective π-co