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A critical review of the emerging field of MOF-based catalysis is presented. Discussed are examples of: (a) opportunistic catalysis with metal nodes, (b) designed catalysis with framework nodes, (c) catalysis by homogeneous catalysts incorporated as framework struts, (d) catalysis by MOF-encapsulated molecular species, (e) catalysis by metal-free organic struts or cavity modifiers, and (f) catalysis by MOF-encapsulated clusters (66 references).

Liquid Nanocrystals In high-resolution transmission electron microscopy, grid materials are used to support solid samples while providing a means for preventing a build-up of static charge. Liquids are difficult to study at the same atomic resolution and require encapsulation to prevent excess sample movement, sample damage, or evaporation. Materials that have been used for liquid cells, like silicon nitride or silicon oxide, need thick layers and have poor electron transmittance at the thicknes

Fan-shaped electrodes were designed on Si∕SiO2 substrate to measure the anisotropic field effect mobility in freestanding single crystal pentacene. Field effect transistor was fabricated by placing single crystal pentacene on the prepatterned electrodes. The contact between the electrodes and single crystal pentacene was enhanced by applying pressure. Angle dependence of field effect mobility in single crystal pentacene showed remarkably anisotropic behavior. The highest mobility value was estim

Abstract Crossbar‐type bipolar resistive memory devices based on low‐temperature amorphous TiO 2 ( a‐ TiO 2 ) thin films are very promising devices for flexible nonvolatile memory applications. However, stable bipolar resistive switching from amorphous TiO 2 thin films has only been achieved for Al metal electrodes that can have severe problems like electromigration and breakdown in real applications and can be a limiting factor for novel applications like transparent electronics. Here, amorphou

In this work, we use in situ transmission electron microscopy (TEM) to investigate the thermal decomposition that occurs at the surface of charged Li x Ni y Mn z Co 1– y – z O 2 (NMC) cathode materials of different composition (with y, z = 0.8, 0.1, and 0.6, 0.2, and 0.4,and 0.3), after they have been charged to their practical upper limit voltage (4.3 V). By heating these materials inside the TEM, we are able to directly characterize near surface changes in both their electronic structure (usin

Abstract Novel multifunctional magnetic gold nanocomposites (MGNCs) were synthesized for synchronous cancer therapy and diagnosis via magnetic resonance imaging (MRI). The MGNCs consist of magnetic kernels (aggregates of ultra‐sensitive MnFe 2 O 4 magnetic nanocrystals wrapped in polymer) as effective MR contrast agents and silica–gold nanocomposites as hyperthermal therapeutic agents. A therapeutic antibody, Erbitux (ERB), was conjugated for specific tumor cell targeting both to localize the ne

Recent real-time analyses have provided invaluable information on the volume expansion of silicon (Si) nanomaterials during their electrochemical reactions with lithium ions and have thus served as useful bases for robust design of high capacity Si anodes in lithium ion batteries (LIBs). In an effort to deepen the understanding on the critical first lithiation of Si, especially in realistic liquid environments, herein, we have engaged in situ graphene liquid cell transmission electron microscopy

Using in situ transmission electron microscopy, we demonstrated that gold nanoparticles are unified via "oriented attachment" assisted either by nanoparticle rotation or grain boundary migration at the attachment interface. We also observed that the combined nanoparticle changes shape with stable facet planes via surface diffusion, along with recrystallization.