송광호 교수

Nickel-catalyzed aminocarbonylation of aryl halides is described. A well-defined air-stable nickel-phosphite catalytic system (Ni(OAc)(2).4H(2)O/phosphite 1) effectively promoted the aminocarbonylation of aryl bromides with a range of formamides to give the corresponding aryl amide products in moderate to good yields. The less hindered formamide required lower catalytic loading for full conversion and produced higher yields than the more hindered one. It also exhibited base-dependent activity to

A trifluoroethylation of alkynes through a palladium-catalyzed decarboxylative coupling reaction was developed. When alkynyl carboxylic acids and ICH2CF3 were allowed to react with [Pd(η(3)-allyl)Cl]2/XantPhos and Cs2CO3 in N,N-dimethylformamide (DMF) at 80 °C for 1 h, the desired products were formed in good yields. This catalytic system showed high functional group tolerance.

Abstract Copper‐catalyzed one‐pot three‐component reactions of 2‐iodoanilines, aldehydes, and NaSH · n H 2 O afford benzothiazoles in good yields. When CuCl was employed as a catalyst in the absence of a ligand, a variety of aromatic aldehydes and substituted 2‐iodoanilines reacted with NaSH · n H 2 O to produce the corresponding 2‐arylbenzothiazoles in 70–98 % yields. The copper catalyst plays a key role in C–S bond formation between NaSH · n H 2 O and the aryl iodide that was formed from the c

In order to screen potential catalytic materials for synthesis and decomposition of ammonia, a series of ABO 3 perovskite materials, Sr 1– x Y x Ti 1– y Ru y O 3−δ ( x = 0, 0.08, and 0.16; y = 0, 0.04, 0.07, 0.12, 0.17, and 0.26) were synthesized and tested for ammonia dehydrogenation. The influence of A or B site substitution on the catalytic ammonia dehydrogenation activity was determined by varying the quantity of either A or B site cation, producing Sr 1 – x Y x Ti 0.92 Ru 0.08 O 3−δ and Sr

Abstract Alkynyl amides were synthesized from a palladium‐catalyzed coupling reaction of alkynyl carboxylic acids and amines under carbon monoxide. The reaction was conducted with palladium(II) acetate (5 mol‐%) and silver(I) oxide (1.0 equiv.) in acetonitrile at 80 °C for 1 h. This method provides good to moderate product yields and good functional group tolerance towards ketone, ester, and nitrile groups.

Hydrogen production from renewable resources, such as lignocellulosic biomass, is highly desired, under the most sustainable and mildest reaction conditions. In this study, a new sustainable three-step process for the production of hydrogen has been proposed. In the first step, a crude formic acid (CF) solution, which included typical reaction byproducts, in particular, acetic acid, levulinic acid, saccharides, 5-hydroxymethylfurfural, furfural, and lignin, was obtained through the combined hydr

Abstract The three‐component reaction of aryl halides, sodium sulfide pentahydrate (Na 2 S⋅5 H 2 O), and propiolic acid in the presence of 2.5% bis(triphenylphosphine)palladium chloride [Pd(PPh 3 ) 2 Cl 2 ], 5% 1,4‐bis(diphenylphosphino)butane (dppb) and 2 equivalents of 1,8‐diazabicycloundec‐7‐ene (DBU) produces stereoselectively ( Z )‐3‐arylthioacrylic acids in good yields. A study of the reaction pathway suggested that the CS bond formation between aryl halides and Na 2 S⋅5 H 2 O proceeded f

Abstract Liquid organic hydrogen carriers (LOHCs) are emerging as a promising solution for global hydrogen logistics. The LOHC process involves two primary chemical reactions: hydrogenation for hydrogen storage and dehydrogenation for hydrogen reconversion. In the exothermic hydrogenation reaction, hydrogen‐lean compounds are converted to hydrogen‐rich compounds, storing hydrogen from various sources such as water electrolysis, fossil fuel reforming, biomass processing, and industrial by‐product

Polystyrene-based polymers with variable molecular weights are prepared by radical polymerization of styrene. Polystyrene is grafted with bromo-alkyl chains of different lengths through Friedel–Crafts acylation and quaternized to afford a series of hydroxide-ion-conducting ionomers for the catalyst binder for the membrane electrode assembly in anion-exchange membrane fuel cells (AEMFCs). Structural analyses reveal that the molecular weight of the polystyrene backbone ranges from 10,000 to 63,000