안남영 교수

High efficiency perovskite solar cells were fabricated reproducibly via Lewis base adduct of lead(II) iodide. PbI2 was dissolved in N,N-dimethyformamide with equimolar N,N-dimethyl sulfoxide (DMSO) and CH3NH3I. Stretching vibration of S═O appeared at 1045 cm(-1) for bare DMSO, which was shifted to 1020 and 1015 cm(-1) upon reacting DMSO with PbI2 and PbI2 + CH3NH3I, respectively, indicative of forming the adduct of PbI2·DMSO and CH3NH3I·PbI2·DMSO due to interaction between Lewis base DMSO and/or

Perovskite solar cells have shown unprecedent performance increase up to 22% efficiency. However, their photovoltaic performance has shown fast deterioration under light illumination in the presence of humid air even with encapulation. The stability of perovskite materials has been unsolved and its mechanism has been elusive. Here we uncover a mechanism for irreversible degradation of perovskite materials in which trapped charges, regardless of the polarity, play a decisive role. An experimental

Mismatch of current (I)-voltage (V) curves with respect to the scan direction, so-called I-V hysteresis, raises critical issue in MAPbI3 (MA = CH3NH3) perovskite solar cell. Although ferroelectric and ion migration have been proposed as a basis for the hysteresis, origin of hysteresis has not been apparently unraveled. We report here on the origin of I-V hysteresis of perovskite solar cell that was systematically evaluated by the interface-dependent electrode polarizations. Frequency (f)-depende

With rapid and brilliant progress in performance over recent years, perovskite solar cells have drawn increasing attention for portable power source applications.

Highly efficient transparent conductive oxide (TCO)-free perovskite (CH3NH3PbI3) solar cells are demonstrated by using a graphene transparent anode and organic carrier transport materials. By adding a few nanometer-thick MoO3 layer, wettability and work function of the graphene electrode are enhanced to enable a 17.1% power conversion efficiency, which is so far the highest efficiency for TCO-free solar cells. As a service to our authors and readers, this journal provides supporting information

By employing the neutral plane concept, we demonstrated ultra-flexible perovskite solar cells that can withstand 100 cycles of crumpling.

Abstract Colloidal quantum dots (QDs) are attractive materials for realizing solution-processable laser diodes that could benefit from size-controlled emission wavelengths, low optical-gain thresholds and ease of integration with photonic and electronic circuits 1–7 . However, the implementation of such devices has been hampered by fast Auger recombination of gain-active multicarrier states 1,8 , poor stability of QD films at high current densities 9,10 and the difficulty to obtain net optical g

Transparent carbon electrodes, carbon nanotubes, and graphene were used as the bottom electrode in flexible inverted perovskite solar cells. Their photovoltaic performance and mechanical resilience were compared and analyzed using various techniques. Whereas a conventional inverted perovskite solar cells using indium tin oxide showed a power conversion efficiency of 17.8%, the carbon nanotube- and graphene-based cells showed efficiencies of 12.8% and 14.2%, respectively. An established MoO 3 dop

It is certain that perovskite materials must be a game-changer in the solar industry as long as their stability reaches a level comparable with the lifetime of a commercialized Si photovoltaic. However, the operational stability of perovskite solar cells and modules still remains unresolved, especially when devices operate in practical energy-harvesting modes represented by maximum power point tracking under 1 sun illumination at ambient conditions. This review article covers from fundamental as

Abstract A simple, low‐cost, large area, and continuous scalable coating method is proposed for the fabrication of hybrid organic–inorganic perovskite solar cells. A megasonic spray‐coating method utilizing a 1.7 MHz megasonic nebulizer that could fabricate reproducible large‐area planar efficient perovskite films is developed. The coating method fabricates uniform large‐area perovskite film with large‐sized grain since smaller and narrower sized mist droplets than those generated by existing ul

Carbon-sandwiched perovskite solar cells have long-term stability and are low cost.

We report a theoretical analysis on the crystallization of CH₃NH₃PbI₃and the control of grain sizes by varying the two-step reaction temperature from −10 °C to 50 °C based on the present analysis.

Lasers and optical amplifiers based on solution-processable materials have been long-desired devices for their compatibility with virtually any substrate, scalability, and ease of integration with on-chip photonics and electronics. These devices have been pursued across a wide range of materials including polymers, small molecules, perovskites, and chemically prepared colloidal semiconductor nanocrystals, also commonly referred to as colloidal quantum dots. The latter materials are especially at