김성수 교수

A family of mesoporous molecular sieves (denoted MSU-G) with vesiclelike hierarchical structures and unprecedented thermal (1000 degreesC) and hydrothermal stabilities (more than 150 hours at 100 degreesC) associated with high SiO4 cross-linking was prepared through a supramolecular assembly pathway that relies on hydrogen bonding between electrically neutral gemini surfactants of the type CnH2n+1NH(CH2)2NH2 and silica precursors derived from tetraethylorthosilicate. The vesicle shells are const

Two-dimensional, hexagonally ordered silicas with large uniform mesopores (7.6−11.9 nm) have been assembled through a nonionic supramolecular assembly pathway using sodium silicate as a silica source and the triblock copolymer Pluronic P123 (EO 20 PO 70 EO 20 ) as a structure-directing agent. An increase in the synthesis temperature from 308 to 333 K in a one-step procedure led to a systematic increase in the unit-cell size, pore diameter, specific surface area, and pore volume, and to a decreas