조성오 교수

Superhydrophobic bionic surfaces with hierarchical micro/nano structures were synthesized by decorating single-walled or multiwalled carbon nanotubes (CNTs) on monolayer polystyrene colloidal crystals using a wet chemical self-assembly technique and subsequent surface treatment with a low surface-energy material of fluoroalkylsilane. The bionic surfaces are based on the regularly ordered colloidal crystals, and thus the surfaces have a uniform superhydrophobic property on the whole surface. More

A sonication-assisted sequential chemical bath deposition (S-CBD) approach is presented to uniformly decorate CdS quantum dots (QDs) on self-organized TiO2 nanotube arrays (TNTAs). This approach avoids the clogging of CdS QDs at the TiO2 nanotube mouth and promotes the deposition of CdS QDs into the nanotubes as well as on the tube walls. The photoelectrochemical and photocatalytic properties of the resulting CdS-decorated TNTAs were explored in detail. In comparison with a classical S-CBD appro

A straightforward and effective polyol route for the controllable synthesis of high-quality gold (Au) octahedra with uniform size is presented in an ethylene glycol solution. Large-scale Au octahedra with the size ranging from tens to hundreds of nanometers were selectively synthesized in high-yield. The surfaces of octahedral Au nanocrystals are smooth and correspond to {111} planes. Formation of Au nanooctahedra was attributed to the preferential adsorption of cationic surfactant poly(diallyld

A novel one-step sonochemical approach to synthesize a plasmonic photocatalyst of AgCl nanocubes (ca. 115 nm in edge length) with a small amount of Ag metal species is presented. The nanoscale Ag/AgCl hybrid photocatalysts with cubic morphology are readily formed under ambient ultrasonic conditions and neither external heat treatment nor reducing agents are required. The size of the Ag/AgCl photocatalysts could be controlled by changing the concentrations of Ag(+) ions and polyvinylpyrrolidone m

We improve the conversion efficiency of Ag2S quantum dot (QD)-sensitized TiO2 nanotube-array electrodes by chemically depositing ZnO recombination barrier layer on plain TiO2 nanotube-array electrodes. The optical properties, structural properties, compositional analysis, and photoelectrochemistry properties of prepared electrodes have been investigated. It is found that for the prepared electrodes, with increasing the cycles of Ag2S deposition, the photocurrent density and the conversion effici

An unconventional and straightforward route to fabricate morphology-controlled 2D ordered carbonaceous nanoarrays is presented. This route is based on the electron irradiation of a polystyrene colloidal monolayer followed by thermal decomposition. This strategy has the advantages of low-cost fabrication and easy manipulation compared to conventional lithography technique and furthermore overcomes the disadvantage of the self-assembly technique that generally has the defect of irregular units in

We present a facile route to prepare bionic superhydrophobic coatings with striking supporting forces by fabricating hierarchical micro-/nanostructures on curved surfaces. The hierarchical structure was synthesized by decorating silver nanoparticles on a monolayer array of polystyrene (PS) microspheres. The monolayer array formed on a flat surface was transferred on a curved surface using silver acetate solution, which can then be converted into silver nanoparticles through thermal decomposition

Immer acht: Einkristalline Au-Nanooktaeder mit genau definierter Form und einstellbarer Größe konnten mit einem modifizierten Polyolprozess hergestellt werden. Die oktaedrischen Au-Nanokristalle haben scharfe Ecken und optische Eigenschaften, die empfindlich auf die Kristallgröße und das Abschneiden von Spitzen reagieren. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2007/z604167_s.pdf or from the author. Please note: The publisher

A thin layer of CuInS2 and CdS quantum dots (QDs) is deposited on TiO2 nanotube arrays (TNTs) to form CdS/CuInS2/TNTs photoelectrodes. The CuInS2 layer is prepared by a successive ionic layer absorption and reaction method, and the CdS QDs are deposited by a chemical bath deposition method. The CuInS2 layer acts as both a co-sensitizer and an energy barrier layer between TNTs and CdS QDs. The deposited CuInS2 layer significantly extends the visible-light response of CdS-sensitized TNTs into 500–

Tuning the electronic band structures such as band-edge position and bandgap of organic semiconductors is crucial to maximize the performance of organic photovoltaic devices. We present a simple yet effective electron irradiation approach to tune the band structure of [6, 6]-phenyl-C61-butyric acid methyl ester (PCBM) that is the most widely used organic acceptor material. We have found that the lowest unoccupied molecular orbital (LUMO) level of PCBM up-shifts toward the vacuum energy level, wh

A simple and straightforward approach to prepare TiO2-coated carbon nanotubes (CNTs) is presented. Anatase TiO2 nanoparticles (NPs) with the average size ~8 nm were coated on CNTs from peroxo titanic acid (PTA) precursor even at low temperature of 100 °C. We demonstrate the effects of CNTs/TiO2 molar ratio on the adsorption capability and photocatalytic efficiency under UV-visible irradiation. The samples showed not only good optical absorption in visible range, but also great adsorption capacit

A vacuum-sealed miniature X-ray tube based on a carbon nanotube field-emission electron source has been demonstrated. The diameter of the X-ray tube is 10 mm; the total length of the tube is 50 mm, and no external vacuum pump is required for the operation. The maximum tube voltage reaches up to 70 kV, and the X-ray tube generates intense X-rays with the air kerma strength of 108 Gy·cm2 min-1. In addition, X-rays produced from the miniature X-ray tube have a comparatively uniform spatial dose dis