송태섭 교수

Silicon is a promising candidate for electrodes in lithium ion batteries due to its large theoretical energy density. Poor capacity retention, caused by pulverization of Si during cycling, frustrates its practical application. We have developed a nanostructured form of silicon, consisting of arrays of sealed, tubular geometries that is capable of accommodating large volume changes associated with lithiation in battery applications. Such electrodes exhibit high initial Coulombic efficiencies (i.e

Crystalline–amorphous phase boundary engineering can be an effective strategy to develop cost-effective and high-performance electrocatalysts for water splitting.

Abstract Proton‐exchange‐membrane water electrolysis (PEMWE) requires an efficient and durable bifunctional electrocatalyst for the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Herein, Ir‐based electrocatalyst is designed using the high entropy alloy (HEA) platform of ZnNiCoIrX with two elements (X: Fe and Mn). A facile dealloying in the vacuum system enables the construction of a nanoporous structure with high crystallinity using Zn as a sacrificial element. Especially

Problems related to tremendous volume changes associated with cycling and the low electron conductivity and ion diffusivity of Si represent major obstacles to its use in high-capacity anodes for lithium ion batteries. We have developed a group IVA based nanotube heterostructure array, consisting of a high-capacity Si inner layer and a highly conductive Ge outer layer, to yield both favorable mechanics and kinetics in battery applications. This type of Si/Ge double-layered nanotube array electrod

Abstract The development of efficient and stable catalyst systems with low‐cost, abundant, and non‐toxic materials is the primary demand for electrochemical water oxidation. A unique method is reported for the syntheses of metal hydroxide carbonate templated Prussian blue analogues (PBAs) on carbon cloth and their outstanding water oxidation activities in alkaline medium. The best water oxidation activity is obtained with cobalt hydroxide carbonate templated t‐Co II ‐Co III with an overpotential

Abstract Borophosphate materials are promising electrocatalysts for water splitting. Their structural flexibility enable self‐adjusting of electronic structure depending on potential. The rich chemistry of borophosphate provides a huge engineering space to tune composition and structure. Herein, amorphized LiNiFe borophosphate (a‐LNFBPO) for an efficient and durable oxygen evolution reaction (OER) is first reported. Facile adsorption of oxygen intermediates on the vacancies generated by spontane

This article overviews the recent progress in TiO₂ (i) as an anode material for Li ion batteries and (ii) as a supplemental material in lithium batteries.

A key issue with Na-ion batteries is the development of active materials with stable electrochemical reversibility through the understanding of their sodium storage mechanisms. We report a sodium storage mechanism and properties of a new anode material, digenite Cu_1.8S, based on its crystallographic study. It is revealed that copper sulfides (Cu _xS) can have metal-rich formulas ( x ≥ 1.6), due to the unique oxidation state of +1 found in group 11 elements. These phases enab

The electrocatalytic performance of transition metal sulfide (TMS)–graphene composites has been simply regarded as the results of high conductivity and the large surface/volume ratio. However, unavoidable factors such as degree of oxidation of TMSs have been hardly considered for the origin of this catalytic activity of TMS–graphene composites. To accomplish the reliable application of TMS-based electrocatalytic materials, a clear understanding of the thermodynamic stability of TMS and effects o

Sb-based materials are promising electrode candidates for rechargeable batteries because of their high electrochemical performance and relatively low cost.

Germanium holds great potential as an anode material for lithium ion batteries due to its large theoretical energy density and excellent intrinsic properties related to its kinetics associated with lithium and electrons. However, the problem related to the tremendous volume change of Ge during cycling is the dominant obstacle for its practical use. The previous research has focused on the improvement in mechanics associated with lithium without consideration of the kinetics. In this study, we de

Abstract Metal–metalloid compounds have been paid much attention as new high‐performance water oxidation catalysts due to their exceptional durability for water oxidation in alkaline media originating from the multi‐dimensional covalent bonding of the metalloid with the surrounding metal atoms. However, compared to the excellent stability, a relatively low catalytic activity of metal‐metalloids often limits their practical application as high‐performance water oxidation catalysts. Here, for the

Graphene oxide quantum dots (GOQDs) are usually prepared using expensive carbon precursors such as carbon nanotubes (CNT) or graphene under the strong acidic condition, which requires an additional purifying process. Here, we first develop a facile pulsed laser ablation in liquid (PLAL) technique for preparing GOQDs using earth-abundant and low-cost coal as a precursor. Only ethanol and coal are used to produce GOQDs with excellent optical properties. The prepared GOQDs exhibit excellent optoele

A facile and scalable process for the formation of artificial SEI layer is proposed by roll-press Li metal and fluoropolymer. The layer, composed of lithium fluoride and polymers, plays Li protection for highly stable lithium metal batteries.