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The morphological and compositional changes of the solid electrolyte interphase (SEI) layer formed on the surface of Si thin electrodes during precycling were investigated. At the beginning of charging, the native layer ( and silanol) covering the surface of the Si thin electrode is readily destroyed and a new SEI layer is formed by the decomposition of both organic solvents and anions. At this stage, the interfacial resistance decreases to a minimum level. Thereafter, the interfacial resistance

A highly adhesive and thermally stable copolyimide (P84) that is soluble in organic solvents is newly applied to silicon (Si) anodes for high energy density lithium-ion batteries. The Si anodes with the P84 binder deliver not only a little higher initial discharge capacity (2392 mAh g(-1)), but also fairly improved Coulombic efficiency (71.2%) compared with the Si anode using conventional polyvinylidene fluoride binder (2148 mAh g(-1) and 61.2%, respectively), even though P84 is reduced irrevers

The adhesion strength of lithium-ion battery (LIB) electrodes consisting of active material, a nanosized electric conductor, and a polymeric binder is measured with a new analysis tool, called the Surface and Interfacial Cutting Analysis System (SAICAS). Compared to the conventional peel test with the same electrode, SAICAS gives higher adhesion strength owing to its elaborate cutting-based measurement system. In addition, the effects on the adhesion property of the polymeric binder type and con

Abstract Making Li metal batteries (LMBs) with thinner Li is necessary to improve the cell energy density in practice. Li metal powders (LMPs) are beneficial for the facile manufacturing of thin Li, flexible cell design, and the 3D control of Li plating/stripping. However, the inhomogeneous surfaces of commercial LMPs limit their practical use in LMBs. Herein, a 20 µm‐thick, LiNO 3 preplanted LMP (LN‐LMP) composite electrode, rationally designed for LMP surface stabilization, is presented. The a

The synergistic effect of different types of conductive additives, vapor-grown carbon fibers (VGCF) and carbon black (Super-P) on the cathode performance of lithium-ion batteries was investigated.

Mesoporous silicon nanofibers (m-SiNFs) have been fabricated using a simple and scalable method via electrospinning and reduction with magnesium. The prepared m-SiNFs have a unique structure in which clusters of the primary Si nanoparticles interconnect to form a secondary three-dimensional mesoporous structure. Although only a few nanosized primary Si particles lead to faster electronic and Li(+) ion diffusion compared to tens of nanosized Si, the secondary nanofiber structure (a few micrometer

Abstract The digital twin technique has been broadly utilized to efficiently and effectively predict the performance and problems associated with real objects via a virtual replica. However, the digitalization of twin electrochemical systems has not been achieved thus far, owing to the large amount of required calculations of numerous and complex differential equations in multiple dimensions. Nevertheless, with the help of continuous progress in hardware and software technologies, the fabricatio