이윤정 교수

Development of materials that deliver more energy at high rates is important for high-power applications, including portable electronic devices and hybrid electric vehicles. For lithium-ion (Li+) batteries, reducing material dimensions can boost Li+ ion and electron transfer in nanostructured electrodes. By manipulating two genes, we equipped viruses with peptide groups having affinity for single-walled carbon nanotubes (SWNTs) on one end and peptides capable of nucleating amorphous iron phospha

Ruthenium-based nanomaterials supported on reduced graphene oxide (rGO) have been investigated as air cathodes in non-aqueous electrolyte Li-air cells using a TEGDME-LiCF3SO3 electrolyte. Homogeneously distributed metallic ruthenium and hydrated ruthenium oxide (RuO2·0.64H2O), deposited exclusively on rGO, have been synthesized with average size below 2.5 nm. The synthesized hybrid materials of Ru-based nanoparticles supported on rGO efficiently functioned as electrocatalysts for Li2O2 oxidation

We propose a feasibility of Co-free Ni-rich Li(Ni(1-x)Mn(x))O2 layer compound. Li(Ni(1-x)Mn(x))O2 (0.1 ≤ x ≤ 0.5) have been synthesized by a coprecipitation method. Rietveld refinement of X-ray diffraction and microscopic studies reveal dense and spherical secondary particles of highly crystalline phase with low cation mixing over the whole compositions, implying successful optimization of synthetic conditions. Electrochemical test results indicated that the Co-free materials delivered high capa

Among many challenges present in Li-air batteries, one of the main reasons of low efficiency is the high charge overpotential due to the slow oxygen evolution reaction (OER). Here, we present systematic evaluation of Pt, Pd, and Ru nanoparticles supported on rGO as OER electrocatalysts in Li-air cell cathodes with LiCF3SO3-tetra(ethylene glycol) dimethyl ether (TEGDME) salt-electrolyte system. All of the noble metals explored could lower the charge overpotentials, and among them, Ru-rGO hybrids

Metal–organic frameworks (MOFs) have the potential to improve the electrochemical performance of Li–O 2 batteries with high O 2 accessibility and catalytic activity of the open metal sites. Here, we explored bimetallic MnCo-MOF-74 as a cathode catalyst in Li–O 2 batteries. MnCo-MOF-74 was synthesized with the Mn to Co ratio of 1:4 by a simple hydrothermal reaction. Compared to monometallic Mn-MOF-74 and Co-MOF-74 with only single catalytic activity for LiOH formation or oxygen evolution reaction

We report the synthesis and electrochemical activity of gold and silver noble metals and their alloy nanowires using multiple virus clones as anode materials for lithium ion batteries. Using two clones, one for specificity (p8#9 virus) and one versatility (E4 virus), noble metal nanowires of high-aspect ratio with diameters below 50 nm were successfully synthesized with control over particle sizes, morphologies, and compositions. The biologically derived noble metal alloy nanowires showed electr

We report the fabrication and electrochemical activity of free-standing reduced graphene oxide (RGO) films as cathode materials for lithium ion batteries. The conducting additive and binder-free RGO electrodes with different oxygen contents were assembled by a simple vacuum filtration process from aqueous RGO colloids prepared with the aid of cationic surfactants. The gravimetric capacity of RGO film cathodes showed clear dependence on the oxygen contents controlled by the thermal reduction proc

Amorphous iron phosphate nanowires with diameters of 10 to 20 nm were synthesized using genetically engineered M13 virus for lithium ion battery cathodes. Hydrolysis of Fe3+ ions has been effectively suppressed by forming conjugates with the virus and synthesizing at low temperature, 4 °C. The M13 virus biological template facilitated elaborate nanostructure design and environmentally benign, low temperature synthesis. By implementing heterostructures with silver, we demonstrated experimentally

Despite the important role of carboxymethyl cellulose (CMC) and styrene-butadiene rubber (SBR) binders in graphite electrodes for Li-ion batteries, the direct analysis of these binders remains challenging, particularly at very low concentrations as in practical graphite anodes. In this paper, we report the systematic investigation of the physiochemical behavior of the CMC and SBR binders and direct observations of their distributions in practical graphite electrodes. The key to this unprecedente

NdBa_0.75Ca_0.25Co₂O_5+δ-based double perovskite catalysts provide new ways for significantly enhanced oxygen-related electrochemical reactions with durable characteristics in alkaline atmospheres.

The structural design and synthesis of effective cathode catalysts are important concerns for achieving rechargeable Li-O 2 batteries. In this study, hexagonal Co 3 O 4 nanoplatelets coated with MnO 2 were synthesized as bifunctional catalysts for Li-O 2 batteries. The oxygen reduction reaction catalyst (MnO 2 ) was closely integrated on the surface of the oxygen evolution reaction catalyst (hexagonal Co 3 O 4 ) so that this hetero-structured catalyst (HSC) hybrid would show bifunctional catalyt

Abstract Increasing demand for flexible devices in various applications, such as smart watches, healthcare, and military applications, requires the development of flexible energy‐storage devices, such as lithium‐ion batteries (LIBs) with high flexibility and capacity. However, it is difficult to ensure high capacity and high flexibility simultaneously through conventional electrode preparation processes. Herein, smart conductive textiles are employed as current collectors for flexible LIBs owing

This review covers various strategies aimed at controlling Li deposition on a heterogeneous current collector for an anodeless cell configuration in batteries with liquid and solid-state electrolytes.

Water purification by membranes is widely investigated to address concerns related to the scarcity of clean water. Achieving high flux and rejection simultaneously is a difficult challenge using such membranes because these properties are mutually exclusive in common artificial membranes. Nature has developed a method for this task involving water-channel membrane proteins known as aquaporins. Here, the design and fabrication of graphene oxide (GO)-based membranes with a surface-tethered peptide