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Reduction of (^ArL)Co^IIBr (^ArL = 5-mesityl-1,9-(2,4,6-Ph₃C₆H₂)dipyrrin) with potassium graphite afforded the novel Co^I synthon (^ArL)Co^I. Treatment of (^ArL)Co^I with a stoichiometric amount of various alkyl azides (N₃R) furnished three-coordinate Co^III alkyl imidos (^ArL)Co(NR), as confirmed by single-crystal X-ray diffraction (R: CMe₂Bu

Treatment of (^ArL)CoBr (^ArL = 5-mesityl-1,9-(2,4,6-Ph₃C₆H₂)dipyrrin) with a stoichiometric amount of 1-azido-4-(<i>tert</i>-butyl)benzene N₃(C₆H₄-<i>p</i>-^<i>t</i>Bu) furnished the corresponding four-coordinate organoazide-bound complex (^ArL)CoBr(N₃(C₆H₄-<i>p</i>-^<i>t</i>Bu)). Spectroscopic and structural characterization of the complex indicat

We report the catalytic C-H amination mediated by an isolable Co^III imido complex (^TrL)Co(NR) supported by a sterically demanding dipyrromethene ligand (^TrL = 5-mesityl-1,9-(trityl)dipyrrin). Metalation of (^TrL)Li with CoCl₂ in THF afforded a high-spin (<i>S</i> = 3/2) three-coordinate complex (^TrL)CoCl. Chemical reduction of (^TrL)CoCl with potassium graphite yielded the high-spin (<i>S</i> = 1) Co^I synthon (

One-electron reduced photosensitizers have been invoked as crucial intermediates in photoredox catalysis, including multiphoton excitation and electrophotocatalytic processes. However, such reduced chromophores have been less investigated, limiting mechanistic studies of their associated electron transfer processes. Here, we report a total of 11 different examples of isolable singly reduced iridium chromophores. Chemical reduction of a cyclometalated iridium complex with potassium graphite affor

Abstract The reactivity of ( Tr L)Co ( Tr L=5‐mesityl‐1,9‐(trityl)dipyrrin) toward various aryl azides was examined to elucidate the electronic structure and reactivity of dipyrrinato cobalt aryl nitrenoid complexes. Herein, we demonstrate the synthesis of a Co II diketimide complex [( Tr L)Co(NC 6 F 5 )] 2 and its reversible C−C bond cleavage to yield a monomeric Co nitrenoid complex ( Tr L)Co(NC 6 F 5 ). Exposure of [( Tr L)Co(NC 6 F 5 )] 2 to an excess amount of an H‐atom donor cleanly afford

Inspired by the prominent redox and optical properties of natural flavins, synthetic flavins have found broad applications in organic, photochemical, and biochemical research. Tailoring these properties of flavins, however, remains a challenge. In this work, we present three pentacyclic flavins (C-PF, O-PF, and S-PF) that leverage a strategic molecular design to modify the flavin’s electronic structure. Notably, the oxygen- and sulfur-linked pentacyclic flavins (O-PF and S-PF) exhibit deep-red a

High Resolution Image Download MS PowerPoint Slide Flavins─one of nature’s most ubiquitous organic cofactors─mediate proton and electron transfers in biological systems. Their heterocyclic (iso)alloxazine cores enable such reactivity through pronounced electro- and photochemical properties, as well as hydrogen bonding with surrounding residues. To harness these features in an organometallic context, we developed a redox-active, flavin-derived bidentate ligand ( all LH ) that engages both primary

Abstract The reactivity of ( Tr L)Co ( Tr L=5‐mesityl‐1,9‐(trityl)dipyrrin) toward various aryl azides was examined to elucidate the electronic structure and reactivity of dipyrrinato cobalt aryl nitrenoid complexes. Herein, we demonstrate the synthesis of a Co II diketimide complex [( Tr L)Co(NC 6 F 5 )] 2 and its reversible C−C bond cleavage to yield a monomeric Co nitrenoid complex ( Tr L)Co(NC 6 F 5 ). Exposure of [( Tr L)Co(NC 6 F 5 )] 2 to an excess amount of an H‐atom donor cleanly afford

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.